Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
Waste Manag. 2018 Jan;71:426-439. doi: 10.1016/j.wasman.2017.09.033. Epub 2017 Oct 9.
Concrete production contributes heavily to greenhouse gas emissions, thus a need exists for the development of durable and sustainable concrete with a lower carbon footprint. This can be achieved when cement is partially replaced with another material, such as waste plastic, though normally with a tradeoff in compressive strength. This study discusses progress toward a high/medium strength concrete with a dense, cementitious matrix that contains an irradiated plastic additive, recovering the compressive strength while displacing concrete with waste materials to reduce greenhouse gas generation. Compressive strength tests showed that the addition of high dose (100kGy) irradiated plastic in multiple concretes resulted in increased compressive strength as compared to samples containing regular, non-irradiated plastic. This suggests that irradiating plastic at a high dose is a viable potential solution for regaining some of the strength that is lost when plastic is added to cement paste. X-ray Diffraction (XRD), Backscattered Electron Microscopy (BSE), and X-ray microtomography explain the mechanisms for strength retention when using irradiated plastic as a filler for cement paste. By partially replacing Portland cement with a recycled waste plastic, this design may have a potential to contribute to reduced carbon emissions when scaled to the level of mass concrete production.
混凝土生产对温室气体排放有很大影响,因此需要开发具有更低碳足迹的耐用和可持续的混凝土。当水泥部分被另一种材料替代时,如废塑料,可以实现这一目标,但通常会牺牲抗压强度。本研究讨论了一种高强度/中强度混凝土的进展,该混凝土具有致密的胶凝基质,其中含有辐照塑料添加剂,在使用废材料替代混凝土以减少温室气体生成的同时恢复抗压强度。抗压强度测试表明,与含有常规非辐照塑料的样品相比,在多种混凝土中添加高剂量(100kGy)辐照塑料会导致抗压强度增加。这表明,对塑料进行高剂量辐照是一种可行的潜在解决方案,可以恢复添加塑料到水泥浆中时失去的部分强度。X 射线衍射(XRD)、背散射电子显微镜(BSE)和 X 射线微断层扫描解释了使用辐照塑料作为水泥浆填充料时保留强度的机制。通过部分用回收废塑料替代波特兰水泥,当这种设计扩展到大规模混凝土生产的水平时,可能有助于减少碳排放。