Institut fur Organische und Biomolekulare Chemie, Georg-August-Universität, Tammannstrasse 2, 37077 Göttingen, Germany.
Department of Chemistry, Institute of Chemical Technology, Matunga, Mumbai-400019, India.
Chem Soc Rev. 2017 Dec 7;46(23):7399-7420. doi: 10.1039/c6cs00787b. Epub 2017 Oct 20.
Fully complementary bimetallic catalysis has been identified as an increasingly powerful tool for molecular transformations, which was largely inspired by early examples of sequential catalytic transformations. Thus, energy-efficient one-pot reactions involving different metal catalysts orchestrated in concert constitute an attractive alternative to multi-step protocols, with major recent progress through the elegant ligand design in heterobimetallic catalysis as well as sustainable photo-induced C-H transformations, among others. This review provides a critical assessment of the state of the art in heterobimetallic catalysis for sustainable organic syntheses (SOS), highlighting key advances and representative examples until summer 2017.
双金属协同催化已被确定为分子转化中日益强大的工具，这在很大程度上受到了序贯催化转化的早期实例的启发。因此，涉及不同金属催化剂的协同作用的节能一锅反应构成了多步方案的有吸引力的替代方案，最近在杂双金属催化中的优雅配体设计以及可持续的光诱导 C-H 转化等方面取得了重大进展。本文对可持续有机合成（SOS）中杂双金属催化的最新进展进行了批判性评估，重点介绍了截至 2017 年夏天的关键进展和代表性实例。
