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生姜干燥根用于银纳米颗粒简单绿色合成的生物还原电位:抗菌研究。

Bioreduction potentials of dried root of Zingiber officinale for a simple green synthesis of silver nanoparticles: Antibacterial studies.

作者信息

Judith Vijaya J, Jayaprakash N, Kombaiah K, Kaviyarasu K, John Kennedy L, Jothi Ramalingam R, Al-Lohedan Hamad A, V M Mansoor-Ali, Maaza M

机构信息

Catalysis and Nanomaterials Research Laboratory, Department of Chemistry, Loyola College, Chennai 600034, India.

Catalysis and Nanomaterials Research Laboratory, Department of Chemistry, Loyola College, Chennai 600034, India; Department of Chemistry, SRM Valliammai Engineering College, Chennai 603203, India.

出版信息

J Photochem Photobiol B. 2017 Dec;177:62-68. doi: 10.1016/j.jphotobiol.2017.10.007. Epub 2017 Oct 7.

Abstract

Green synthesis of silver nanoparticles (Ag NPs) using an extract of dried Zingiber officinale (ginger) root as a reducing and capping agent in the presence of microwave irradiation was herein reported for the first time. The formation of symmetrical spheres is confirmed from the UV-Visible spectrum of Ag NPs. Fourier transform infra-red spectroscopy confirms the formation of the Ag NPs. X-ray diffraction analysis was utilized to calculate the crystallite size of Ag NPs and the value was found to be 10nm. High-resolution transmission electron microscopy and high-resolution scanning electron microscopy were used to investigate the morphology and size of the synthesized samples. The sphere like morphology is confirmed from the images. The purity and crystallinity of Ag NPs is confirmed by energy-dispersive X-Ray analysis and selected area electron diffraction respectively. The electrochemical behavior of the synthesized Ag NPs was assessed by cyclic voltammetry (CV) and shows the redox peaks in the potential range of -1.1 to +1.1V. Agar diffusion method is used to examine the antibacterial activity of Ag NPs. For this purpose, two gram positive and two gram negative bacteria were studied. This single step approach was found to be simple, short time, cost-effective, reproducible, and eco-friendly.

摘要

本文首次报道了在微波辐射下,使用干燥的姜根提取物作为还原剂和封端剂,绿色合成银纳米颗粒(Ag NPs)。从Ag NPs的紫外可见光谱证实了对称球体的形成。傅里叶变换红外光谱证实了Ag NPs的形成。利用X射线衍射分析计算了Ag NPs的微晶尺寸,发现其值为10nm。使用高分辨率透射电子显微镜和高分辨率扫描电子显微镜研究了合成样品的形态和尺寸。从图像中证实了球状形态。分别通过能量色散X射线分析和选区电子衍射确认了Ag NPs的纯度和结晶度。通过循环伏安法(CV)评估了合成的Ag NPs的电化学行为,结果显示在-1.1至+1.1V的电位范围内出现氧化还原峰。采用琼脂扩散法检测Ag NPs的抗菌活性。为此,研究了两种革兰氏阳性菌和两种革兰氏阴性菌。发现这种单步方法简单、耗时短、成本效益高、可重复且环保。

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