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牙科用甲基丙烯酸树脂的研究。(第6部分)自凝甲基丙烯酸树脂对具有不同交联密度的聚甲基丙烯酸甲酯的粘结强度。(作者译)

[Studies of dental methacrylic resin. (Part. 6) Adhesive strength of self-curing methacrylic resin to polymethylmetacrylates with various cross-linking density. (author's transl)].

作者信息

Hirasawa T, Hirabayashi S, Harashima I

出版信息

Shika Rikogaku Zasshi. 1979 Apr;20(50):85-93.

PMID:290711
Abstract

The adhesive property of dental acrylic resin to resin teeth and denture base resins is an important property, in the case of preperating, repairing and rebasing denture. Then, as models of denture base resin and resin tooth, heat-curing methacrylic resins which were cross-linked with three kinds of polyethylene glycol dimethacrylate, i.e., EDMA, tri-EDMA, nona-EDMA, were prepared, and the tensile adhesive strengths of self-curing methacrylic resin to them were examined. The results were as follows. 1) The tensile adhesive strength under the dry condition was dependent on cross-linking density of adherent resin, and decreased according to the increase of concentration of cross-linking agent added in adherent resin. 2) The greater the number of chain members of cross-linking agent used to adherent resin was, the higher the adhesive strength was. In particular, the adhesive strength to adherent resin added with nona-EDMA in concentration from 16.7 to 30 mole%, agreed with the tensile strength of adherent resin itself indicating a favourable adhesion. 3) The adhesive strengths under the wet condition, that is, when specimens were immersed in water at 37 degrees C for 21 days, decreased from 30 to 50%, compared with that under the dry condition.

摘要

在义齿制备、修复和重衬的情况下,牙科丙烯酸树脂对树脂牙和义齿基托树脂的粘结性能是一项重要性能。然后,制备了用三种聚乙二醇二甲基丙烯酸酯(即EDMA、三乙二胺甲基丙烯酸酯、九乙二胺甲基丙烯酸酯)交联的热固化甲基丙烯酸树脂作为义齿基托树脂和树脂牙的模型,并测试了自固化甲基丙烯酸树脂对它们的拉伸粘结强度。结果如下:1)干燥条件下的拉伸粘结强度取决于粘附树脂的交联密度,并随着粘附树脂中交联剂添加浓度的增加而降低。2)用于粘附树脂的交联剂链节数越多,粘结强度越高。特别是,对添加了浓度为16.7%至30摩尔%的九乙二胺甲基丙烯酸酯的粘附树脂的粘结强度,与粘附树脂本身的拉伸强度一致,表明粘结良好。3)在潮湿条件下,即当试样在37℃水中浸泡21天时,粘结强度比干燥条件下降低了30%至50%。

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