Aix-Marseille University, IUSTI UMR CNRS 7343, Marseille, France.
Chem Soc Rev. 2018 Jan 22;47(2):558-585. doi: 10.1039/c6cs00902f.
The wetting of solid surfaces using liquid droplets has been studied since the early 1800s. Thomas Young and Pierre-Simon Laplace investigated the wetting properties, as well as the role of the contact angle and the coupling of a liquid and solid, on the contact angle formation. The geometry of a sessile droplet is relatively simple. However, it is sufficiently complex to be applied for solving and prediction of real-life situations (for example, metallic inks for inkjet printing, the spreading of pesticides on leaves, the dropping of whole blood, the spreading of blood serum, and drying for medical applications). Moreover, when taking into account both wetting and evaporation, a simple droplet becomes a very complex problem, and has been investigated by a number of researchers worldwide. The complexity is mainly due to the physics involved, the full coupling with the substrate upon which the drop is deposited, the atmosphere surrounding the droplet, and the nature of the fluid (pure fluid, bi- or multi-phase mixtures, or even fluids containing colloids and/or nano-particles). This review presents the physics involved during droplet wetting and evaporation by focusing on the evaporation dynamics, the flow motion, the vapour behaviour, the surface tension, and the wetting properties.
自 19 世纪初以来,人们就一直在研究使用液滴润湿固体表面。托马斯·杨和皮埃尔-西蒙·拉普拉斯研究了润湿特性,以及接触角和液体与固体的耦合在接触角形成中的作用。固着液滴的几何形状相对简单。然而,它足够复杂,可以应用于解决和预测现实生活中的情况(例如,喷墨打印用的金属油墨、农药在叶片上的扩散、全血滴下、血清扩散和医疗应用中的干燥)。此外,当同时考虑润湿和蒸发时,一个简单的液滴就变成了一个非常复杂的问题,已经有许多研究人员在世界各地进行了研究。这种复杂性主要是由于涉及的物理现象、与液滴沉积的基底的完全耦合、围绕液滴的大气以及流体的性质(纯流体、双相或多相混合物,甚至包含胶体和/或纳米颗粒的流体)。本文通过关注蒸发动力学、流动运动、蒸汽行为、表面张力和润湿特性,介绍了液滴润湿和蒸发过程中的物理现象。