Pb(II) sorption from aqueous solution by novel biochar loaded with nano-particles.

Novel sorbent (HBC) is prepared by introducing nano-particles (Maghemite and EDTA functionalized layered double hydroxides) on biochar surface. FTIR, XRD, SEM and EDS are used to characterize the biochar nanocomposites. Pb(II) sorption is highly dependent on solution pH. Sorption kinetics and isotherms indicate that Pb(II) sorption onto the sorbents follows pseudo-second order model and Langmuir isotherm. The maximum sorption capacity of Pb(II) onto HBC is up to146.84 mg g, higher than previously reported sorbents. The magnetic particles enable easy separation of HBC from aqueous solution by external magnetic fields. HBC can be used as effective sorbent for removal of heavy metals from wastewater.