a Water Treatment and Desalination Unit, Desert Research Center , Cairo , Egypt.
b Soil Fertility and Microbiology Dept. , Desert Research Center , Cairo , Egypt.
J Environ Sci Health A Tox Hazard Subst Environ Eng. 2018 Feb 23;53(3):205-212. doi: 10.1080/10934529.2017.1387012. Epub 2017 Nov 17.
Co-precipitation method was used for preparation of two types of iron oxide nanoparticles coated by titanium dioxide according to divalent salts used. The average size of iron oxide nanoparticles coated by titanium dioxide measured by particle size analyzer, ranged approximately between 20 nm and 100 nm with mean particle size of 60 nm. Characterization of the prepared nanoparticles was done by X-ray diffraction analysis and scanning electron microscope indicating the sole existence of inverse cubic spinel phase of magnetic iron oxide nanoparticles. Further, the antibacterial activity of two prepared iron oxide nanoparticles was evaluated against four pathogenic bacteria where both preparations showed promising antibacterial activities against Gram positive and Gram negative strains which offers a potential application in pharmaceutical and biomedical industries. The antibacterial activity showed high reduction percent after 30 min by 150 μg mL of nanoparticles prepared. Also, high reduction percent was achieved for removal of iron and manganese ions from polluted water and good effect on decreasing chemical oxygen demand and biochemical oxygen demand concentrations with decreased percent of total nitrogen concentration.
共沉淀法是根据使用的二价盐制备两种类型的二氧化钛包覆氧化铁纳米粒子。通过粒度分析仪测量的二氧化钛包覆氧化铁纳米粒子的平均粒径约为 20nm 至 100nm,平均粒径为 60nm。通过 X 射线衍射分析和扫描电子显微镜对制备的纳米粒子进行了表征,表明仅存在磁性氧化铁纳米粒子的反尖晶石相。此外,还评估了两种制备的氧化铁纳米粒子对四种病原菌的抗菌活性,结果表明,两种制剂对革兰氏阳性菌和革兰氏阴性菌均表现出良好的抗菌活性,这为制药和生物医学工业提供了潜在的应用。在 30 分钟后,浓度为 150μg mL 的纳米粒子的抗菌活性显示出高的还原百分比。此外,从污染水中去除铁和锰离子也取得了很高的还原百分比,并且对降低化学需氧量和生化需氧量浓度以及降低总氮浓度百分比也有很好的效果。