Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
Research Institute of Electrochemical Energy, National Institute of Advanced Industrial Science and Technology (AIST), 1-8-31 Midorigaoka, Ikeda, Osaka, 563-8577, Japan.
Adv Mater. 2018 Sep;30(37):e1703663. doi: 10.1002/adma.201703663. Epub 2017 Nov 27.
Metal-organic frameworks (MOFs), also called porous coordination polymers, represent a class of crystalline porous materials built from organic linkers and metal ions/clusters. The unique features of MOFs, including structural diversity and tailorability as well as high surface area, etc., enable them to be a highly versatile platform for potential applications in many fields. Herein, an overview of recent developments achieved in MOF catalysis, including heterogeneous catalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided. The active sites involved in the catalysts are particularly emphasized. The challenges, future trends, and prospects associated with MOFs and their related materials for catalysis are also discussed.
金属-有机框架（MOFs），也称为多孔配位聚合物，代表了一类由有机配体和金属离子/簇构建的结晶多孔材料。MOFs 的独特特性，包括结构多样性和可定制性以及高表面积等，使它们成为在许多领域具有广泛应用潜力的多功能平台。本文综述了 MOF 催化领域的最新进展，包括 MOF 和 MOF 基材料在多相催化、光催化和电催化方面的应用。特别强调了催化剂中涉及的活性位点。还讨论了与 MOFs 及其相关材料在催化方面相关的挑战、未来趋势和前景。
