Camarillo-Martínez Gabriela, Martínez-Cano Evelia, Zepeda-Navarro Abraham, Guzmán-Mar Jorge Luis, Bivián-Castro Egla Yareth
Centro Universitario de los Lagos, Universidad de Guadalajara, Av. Enrique Díaz de León 1144, Col. Paseos de la Montaña, Lagos de Moreno 47460, Jalisco, Mexico.
Facultad de Ciencias Químicas, Universidad Autonoma de Nuevo León (UANL), Ave. Universidad s/n, Cd. Universitaria, San Nicolas de los Garza 66455, Nuevo León, Mexico.
Int J Mol Sci. 2025 Jun 16;26(12):5777. doi: 10.3390/ijms26125777.
Metal-organic frameworks or MOFs are coordination polymers consisting of cationic metal centers liked by ligands. These coordination polymers have repeating entities that extend in one, two, or three dimensions through various Metal-ligand covalent bonds. The structural diversity of MOFs allows for the fine-tuning of properties like pore size, stability, and functionality, making them ideal for a wide range of industrial, environmental, and biomedical applications. Basolite C-300, HKUST-1 or [Cu(btc)(HO)], is one of the most studied three-dimensional porous frameworks. It is a commercially available MOF, easily produced under laboratory conditions. Its unique cubic structure, with multiple pore and adsorption sites, enhances its properties. This article reviews the conventional, new, and non-conventional methods of MOF and Basolite C-300 synthesis. In addition, the structural and spectral characterization of Basolite C-300 and its analogues is described, using spectroscopic and complementary multi-techniques to obtain fundamental knowledge about their structure. Finally, the applications of Basolite C-300 and similar MOFs are discussed, emphasizing their importance in industry and materials, technologies aimed at addressing global environmental and energy-related challenges, and biomedical applications.
金属有机框架材料（MOFs）是由配体连接的阳离子金属中心组成的配位聚合物。这些配位聚合物具有通过各种金属-配体共价键在一维、二维或三维方向上延伸的重复单元。MOFs的结构多样性使得其孔径、稳定性和功能性等性质能够得到精细调节，这使其成为广泛应用于工业、环境和生物医学领域的理想材料。Basolite C-300，即HKUST-1或[Cu(btc)(H₂O)]，是研究最多的三维多孔框架材料之一。它是一种可商购的MOF，在实验室条件下易于制备。其独特的立方结构以及多个孔和吸附位点增强了它的性能。本文综述了MOF和Basolite C-300合成的传统方法、新方法和非常规方法。此外，还描述了Basolite C-300及其类似物的结构和光谱表征，使用光谱学和互补多技术来获取有关其结构的基础知识。最后，讨论了Basolite C-300和类似MOFs的应用，强调了它们在工业和材料领域的重要性、旨在应对全球环境和能源相关挑战的技术以及生物医学应用。
