双鞘丝藻内酯B的C1-C13片段的快速对映选择性合成
Rapid, enantioselective synthesis of the C1-C13 fragment of biselyngbyolide B.
作者信息
Thorat Rakesh G, Harned Andrew M
机构信息
Texas Tech University, Department of Chemistry & Biochemistry, 1204 Boston Ave., Lubbock, TX 79409-1061, USA.
出版信息
Chem Commun (Camb). 2018 Jan 2;54(3):241-243. doi: 10.1039/c7cc08004b.
PMID:29199310
Abstract
A rapid synthesis of the C1-C13 fragment of biselynbyolide A and B is reported. The judicious use of catalytic transformations for C-C bond formation and stereocenter generation greatly minimizes the use of protecting groups and oxidation state changes, as compared to previously reported routes to similar fragments.
摘要
报道了双硒联苯内酯A和B的C1-C13片段的快速合成。与先前报道的合成类似片段的路线相比，在形成C-C键和产生立体中心时明智地使用催化转化极大地减少了保护基团的使用和氧化态的变化。
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