使用水溶性蒽醌光催化剂的选择性光氧化反应
Selective Photooxidation Reactions using Water-Soluble Anthraquinone Photocatalysts.
作者信息
Zhang Wuyuan, Gacs Jenő, Arends Isabel W C E, Hollmann Frank
机构信息
Department of Biotechnology Delft University of Technology Van der Maasweg 92629 HZ Delft The Netherlands.
出版信息
ChemCatChem. 2017 Oct 23;9(20):3821-3826. doi: 10.1002/cctc.201700779. Epub 2017 Sep 7.
Abstract
The aerobic organocatalytic oxidation of alcohols was achieved by using water-soluble sodium anthraquinone sulfonate. Under visible-light activation, this catalyst mediated the aerobic oxidation of alcohols to aldehydes and ketones. The photo-oxyfunctionalization of alkanes was also possible under these conditions.
摘要
通过使用水溶性蒽醌磺酸钠实现了醇的需氧有机催化氧化。在可见光活化下，该催化剂介导醇需氧氧化为醛和酮。在这些条件下，烷烃的光氧官能化也是可能的。
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