钯催化双[(频哪醇硼酸酯基)硼基]甲烷的氧化烯丙基化反应：高烯丙基硼酸酯的合成
Palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane: synthesis of homoallylic boronic esters.
作者信息
Li Chunsheng, Li Meng, Li Jianxiao, Wu Wanqing, Jiang Huanfeng
机构信息
Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.
出版信息
Chem Commun (Camb). 2017 Dec 19;54(1):66-69. doi: 10.1039/c7cc07788b.
A palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane to afford the corresponding homoallylic organoboronic esters with moderate to excellent yields is reported. This novel transformation provides an efficient strategy for the construction of homoallylic organoboronic esters in one step with a broad substrate scope. It is proposed that the palladium-catalyzed oxidative allylic C-H bond activation process may be involved in the catalytic cycle.
报道了一种钯催化的双[(频哪醇)硼基]甲烷的氧化烯丙基化反应，可中等至优异产率地得到相应的高烯丙基有机硼酸酯。这种新型转化为一步构建高烯丙基有机硼酸酯提供了一种有效的策略，底物范围广泛。据推测，钯催化的氧化烯丙基C-H键活化过程可能参与催化循环。
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