Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg , Egerlandstraße 3, 91058 Erlangen, Germany.
Department of Chemical and Pharmaceutical Sciences, INSTM UdR Trieste, University of Trieste , Via Licio Giorgieri 1, 34127 Trieste, Italy.
J Am Chem Soc. 2018 Jan 24;140(3):904-907. doi: 10.1021/jacs.7b12434. Epub 2018 Jan 5.
We present an in-depth investigation regarding the electron-accepting nature of pressure-synthesized carbon nanodots (pCNDs) in combination with porphyrins as excited-state electron donors. To this end, electrostatic attractions involving negative charges, which are present on the pCND surface, are essential to govern the hybrid assembly, on one hand, and charge separation, on the other hand.
我们深入研究了在压力合成的碳纳米点（pCND）与卟啉作为激发态电子供体结合时的电子接受性质。为此，一方面，pCND 表面存在的负电荷之间的静电吸引对于控制杂化组装是必不可少的；另一方面，静电吸引对于电荷分离也是必不可少的。
