State Key Laboratory of Cryospheric Science, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou, 730000, China.
University of Chinese Academy of Sciences, Beijing, 100049, China.
Environ Sci Pollut Res Int. 2018 Mar;25(8):7875-7883. doi: 10.1007/s11356-017-0904-3. Epub 2018 Jan 3.
Trace elements (TEs) could pose a potential threat to the environment and human health and hence they have been paid attention increasingly at present. This study presents the acid-leached concentrations of TEs (e.g., Al, As, Ba, Co, Cr, Cs, Cu, Fe, Li, Mn, Mo, Pb, Rb, Sb, Sr, Ti, Tl, U, V) and dust content sampled from Qiumianleike (QMLK), Meikuang (MK), Yuzhufeng (YZF), Xiaodongkemadi (XDKMD), Gurenhekou (GRHK) glaciers on the Tibetan Plateau (TP) from April to May in 2013. A nonparametric Jonckheere-Terpstra Method was used to test the trend of spatial distribution of TEs. The statistical analysis indicates that TEs were the highest in the QMLK glacier, lowest in the YZF glacier, and comparable in the other three glaciers. Comparison with other glaciers of the plateau, the statistical analysis on As, Cu, Mo, Pb, and Sb shows that their concentrations had, in general, a decreasing distribution characteristic from the north to the south of TP, which indicates that the northern TP is loading more atmospheric-polluted impurity than central and southern TP. Enrichment factor (EF) analysis indicates that Rb, V, U, Cr, Ba, Cs, Li, As, Co, Mn, Tl, Sr, and Cu originated mainly from crustal dust, while anthropogenic inputs such as nonferrous metals melting, coal combustion, and traffic emission made an important contribution to the Mo, Pb, and Sb. Evidences from air mass back trajectories show that TEs in the five studied glaciers might not only come from surrounding areas of glaciers but also might be long-range transported by atmosphere from the Central Asia and South Asia and deposited on these glaciers.
微量元素 (TEs) 可能对环境和人类健康构成潜在威胁,因此目前越来越受到关注。本研究提供了 2013 年 4 月至 5 月从青藏高原采集的取自邱棉来克 (QMLK)、美矿 (MK)、玉珠峰 (YZF)、小冬克马迪 (XDKMD) 和古仁河口 (GRHK) 冰川的酸溶 TE(如 Al、As、Ba、Co、Cr、Cs、Cu、Fe、Li、Mn、Mo、Pb、Rb、Sb、Sr、Ti、Tl、U、V)浓度和粉尘含量数据。采用非参数 Jonckheere-Terpstra 方法检验了 TEs 空间分布趋势。统计分析表明,QMLK 冰川中 TEs 含量最高,YZF 冰川中含量最低,其他三个冰川中含量相当。与高原其他冰川相比,对 As、Cu、Mo、Pb 和 Sb 的统计分析表明,从高原北部到南部,这些元素的浓度呈递减分布特征,这表明高原北部比中南部吸收了更多的大气污染杂质。富集因子 (EF) 分析表明,Rb、V、U、Cr、Ba、Cs、Li、As、Co、Mn、Tl、Sr 和 Cu 主要来源于地壳粉尘,而有色金属冶炼、煤炭燃烧和交通排放等人为输入对 Mo、Pb 和 Sb 有重要贡献。气团轨迹后向轨迹的证据表明,这五个研究冰川中的 TEs 不仅可能来自周围地区,而且可能通过大气长距离传输从中亚和南亚到达这些冰川并沉积下来。