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双轴拉伸下石墨烯片层(GPLs)取向重排对聚合物复合材料杨氏模量的影响

Effects of Reorientation of Graphene Platelets (GPLs) on Young's Modulus of Polymer Composites under Bi-Axial Stretching.

作者信息

Feng Chuang, Wang Yu, Yang Jie

机构信息

School of Engineering, RMIT University, P.O. Box 71, Bundoora, VIC 3083, Australia.

出版信息

Nanomaterials (Basel). 2018 Jan 7;8(1):27. doi: 10.3390/nano8010027.

DOI:10.3390/nano8010027
PMID:29316669
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5791114/
Abstract

Effects of bi-axial stretching induced reorientation of graphene platelets (GPLs) on the Young's modulus of GPL/polymer composites is studied by Mori-Tanaka micromechanics model. The dispersion state of the GPLs in polymer matrix is captured by an orientation distribution function (ODF), in which two Euler angles are used to identify the orientation of the GPLs. Compared to uni-axial stretching, the increase of the stretching strain in the second direction enhances the re-alignment of GPL fillers in this direction while it deteriorates the re-alignment of the fillers in the other two directions. Comprehensive parametric study on the effects of the out-of-plane Young's modulus, stretching strain, strain ratio, Poisson's ratio and weight fraction and GPL dimension on the effective Young's moduli of the composites in the three directions are conducted. It is found that the out-of-plane Young's modulus has limited effects on the overall Young's modulus of the composites. The second stretching enhances the Young's modulus in this direction while it decreases the Young's modulus in the other two directions. The results demonstrate the increase of Poisson's ratio is favorable in increasing the Young's modulus of the composites. GPLs with larger diameter-to-thickness ratio have better reinforcing effect on the Young's modulus of GPL/polymer nanocomposites.

摘要

采用Mori-Tanaka微观力学模型研究了双轴拉伸诱导石墨烯片(GPLs)取向对GPL/聚合物复合材料杨氏模量的影响。通过取向分布函数(ODF)来描述GPLs在聚合物基体中的分散状态,其中使用两个欧拉角来确定GPLs的取向。与单轴拉伸相比,第二方向拉伸应变的增加增强了GPLs在该方向上的重新排列,同时降低了其在其他两个方向上的重新排列。对平面外杨氏模量、拉伸应变、应变比、泊松比、重量分数以及GPL尺寸对复合材料在三个方向上有效杨氏模量的影响进行了综合参数研究。结果发现,平面外杨氏模量对复合材料的整体杨氏模量影响有限。第二次拉伸提高了该方向上的杨氏模量,同时降低了其他两个方向上的杨氏模量。结果表明,泊松比的增加有利于提高复合材料的杨氏模量。直径与厚度比更大的GPLs对GPL/聚合物纳米复合材料的杨氏模量具有更好的增强效果。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/c11acf162ed4/nanomaterials-08-00027-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/a1792163986a/nanomaterials-08-00027-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/002ba3e4a946/nanomaterials-08-00027-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/1b7d53c20106/nanomaterials-08-00027-g003a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/f13b9a77aa0c/nanomaterials-08-00027-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/bbe0dfa948ec/nanomaterials-08-00027-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/bb1968533fdd/nanomaterials-08-00027-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/dbc3678e5278/nanomaterials-08-00027-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/8c77fe21d781/nanomaterials-08-00027-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/79b1d55382df/nanomaterials-08-00027-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/f684f47e21d0/nanomaterials-08-00027-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/c11acf162ed4/nanomaterials-08-00027-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/a1792163986a/nanomaterials-08-00027-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/002ba3e4a946/nanomaterials-08-00027-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/1b7d53c20106/nanomaterials-08-00027-g003a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/f13b9a77aa0c/nanomaterials-08-00027-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/bbe0dfa948ec/nanomaterials-08-00027-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/bb1968533fdd/nanomaterials-08-00027-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/dbc3678e5278/nanomaterials-08-00027-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/8c77fe21d781/nanomaterials-08-00027-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/79b1d55382df/nanomaterials-08-00027-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/f684f47e21d0/nanomaterials-08-00027-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6375/5791114/c11acf162ed4/nanomaterials-08-00027-g011.jpg

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