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凹凸棒石纳米管在清洁、加固和保护中的应用。

Halloysite Nanotubes for Cleaning, Consolidation and Protection.

机构信息

Department of Physics and Chemistry, University of Palermo, Viale delle Scienze, Ed. 17, 90128, Palermo, Italy.

出版信息

Chem Rec. 2018 Jul;18(7-8):940-949. doi: 10.1002/tcr.201700099. Epub 2018 Jan 10.

DOI:10.1002/tcr.201700099
PMID:29320613
Abstract

Herein, we report our recent research concerning the development of halloysite based protocols for cleaning, consolidation and protection purposes. Surface modification of halloysite cavity by anionic surfactants was explored to fabricate inorganic micelles able to solubilize hydrophobic contaminants. Hybrid dispersions based on halloysite and ecocompatible polymers were tested as consolidants for paper and waterlogged archaeological woods. Encapsulation of deacidifying and flame retardant agents within the halloysite lumen was conducted with aim to obtain nanofiller with a long-term protection ability. The results prove the suitability and versatility of halloysite nanotubes, which are perspective inorganic nanoparticles within materials science, remedation and conservation of cultural heritage fields.

摘要

在此,我们报告了我们最近关于基于埃洛石的清洁、加固和保护方案的研究。探索了通过阴离子表面活性剂对埃洛石孔进行表面改性,以制备能够溶解疏水性污染物的无机胶束。基于埃洛石和生态相容聚合物的混合分散体被测试为纸张和水浸考古木材的加固剂。将脱酸和阻燃剂封装在埃洛石管腔中,目的是获得具有长期保护能力的纳米填料。结果证明了埃洛石纳米管的适用性和多功能性,它们是材料科学、修复和保护文化遗产领域有前景的无机纳米粒子。

相似文献

1
Halloysite Nanotubes for Cleaning, Consolidation and Protection.凹凸棒石纳米管在清洁、加固和保护中的应用。
Chem Rec. 2018 Jul;18(7-8):940-949. doi: 10.1002/tcr.201700099. Epub 2018 Jan 10.
2
Halloysite Nanotubes: Interfacial Properties and Applications in Cultural Heritage.埃洛石纳米管:界面特性及其在文化遗产中的应用
Langmuir. 2020 Apr 14;36(14):3677-3689. doi: 10.1021/acs.langmuir.0c00573. Epub 2020 Apr 2.
3
Halloysite Nanotubes Loaded with Calcium Hydroxide: Alkaline Fillers for the Deacidification of Waterlogged Archeological Woods.羟基磷灰石纳米管负载氢氧化钙:水涝考古木材脱酸用碱性填料。
ACS Appl Mater Interfaces. 2018 Aug 15;10(32):27355-27364. doi: 10.1021/acsami.8b09416. Epub 2018 Aug 1.
4
Hydrophobically Modified Halloysite Nanotubes as Reverse Micelles for Water-in-Oil Emulsion.疏水改性埃洛石纳米管作为油包水乳液的反胶束
Langmuir. 2015 Jul 14;31(27):7472-8. doi: 10.1021/acs.langmuir.5b01181. Epub 2015 Jul 2.
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Halloysite nanotubes as nanoreactors for heterogeneous micellar catalysis.埃洛石纳米管作为非均相胶束催化的纳米反应器。
J Colloid Interface Sci. 2022 Feb 15;608(Pt 1):424-434. doi: 10.1016/j.jcis.2021.09.146. Epub 2021 Sep 29.
6
Why does vacuum drive to the loading of halloysite nanotubes? The key role of water confinement.为什么真空有助于埃洛石纳米管的负载?水限制的关键作用。
J Colloid Interface Sci. 2019 Jul 1;547:361-369. doi: 10.1016/j.jcis.2019.04.012. Epub 2019 Apr 4.
7
Pickering Emulsions Based on Wax and Halloysite Nanotubes: An Ecofriendly Protocol for the Treatment of Archeological Woods.基于蜡和埃洛石纳米管的皮克林乳液:一种用于处理考古木材的环保方案。
ACS Appl Mater Interfaces. 2021 Jan 13;13(1):1651-1661. doi: 10.1021/acsami.0c20443. Epub 2020 Dec 30.
8
Selective modification of halloysite lumen with octadecylphosphonic acid: new inorganic tubular micelle.用十八烷基磷酸选择性修饰埃洛石管腔:新型无机管状胶束。
J Am Chem Soc. 2012 Jan 25;134(3):1853-9. doi: 10.1021/ja210258y. Epub 2012 Jan 12.
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Cellulose and Lignin Nano-Scale Consolidants for Waterlogged Archaeological Wood.用于水浸考古木材的纤维素和木质素纳米级加固剂
Front Chem. 2020 Jan 29;8:32. doi: 10.3389/fchem.2020.00032. eCollection 2020.
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Colloid and materials science for the conservation of cultural heritage: cleaning, consolidation, and deacidification.胶体与材料科学在文化遗产保护中的应用:清洗、加固和脱酸。
Langmuir. 2013 Apr 30;29(17):5110-22. doi: 10.1021/la304456n. Epub 2013 Mar 12.

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Physicochemical and Microbiological Assessment of an Experimental Composite Doped with Triclosan-Loaded Halloysite Nanotubes.负载三氯生的埃洛石纳米管掺杂的实验性复合材料的物理化学和微生物学评估
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