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用于从纸质文物中去除真菌和细菌的新型质子离子液体。

New protic ionic liquids for fungi and bacteria removal from paper heritage artefacts.

作者信息

Dimitrić Nataša, Spremo Nemanja, Vraneš Milan, Belić Sanja, Karaman Maja, Kovačević Strahinja, Karadžić Milica, Podunavac-Kuzmanović Sanja, Korolija-Crkvenjakov Daniela, Gadžurić Slobodan

机构信息

Faculty of Science, University of Novi Sad Trg Dositeja Obradovića 3 21000 Novi Sad Serbia

Faculty of Technology, University of Novi Sad Bulevar Cara Lazara 1 21000 Novi Sad Serbia.

出版信息

RSC Adv. 2019 Jun 6;9(31):17905-17912. doi: 10.1039/c9ra03067k. eCollection 2019 Jun 4.

DOI:10.1039/c9ra03067k
PMID:35520586
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9064666/
Abstract

In this work, new protic ionic liquids (PILs) with 1-ammonium-2-propanol cation and nine different anions: formate (For), acetate (Ac), lactate (Lac), trifluoroacetate (TFA), chloroacetate (ClA), trichloroacetate (TClA), 3-chloropropionate (3-ClP), 4-chlorobutyrate (4-ClB) and mandelate (Man) were prepared in order to study their antimicrobial activity and possible application for fungi and bacteria removal from deteriorated paper heritage. Ten filamentous fungal strains isolated from specific pigmented area of the damaged books: sp., sp., sp., , sp., , , eight Gram positive and Gram negative ATCC bacterial strains: , , , , , , , and two yeast strains: and were used in this study. The results indicated that antimicrobial activity of selected ionic liquids is significantly affected by the size and specific functional groups in the anion structure. These facts opened the possibility for molecular design of new ionic liquids with strong inhibition properties against the specific bacterial, mould and yeast strains. The significant antimicrobial properties observed in this research suggest that studied PILs may have potential applications in the paper art and artefact cleaning and conservation replacing thus, conventional solvents and organic substances that are toxic for humans and environment.

摘要

在本研究中，制备了具有1-铵基-2-丙醇阳离子和九种不同阴离子的新型质子离子液体（PILs）：甲酸根（For）、乙酸根（Ac）、乳酸根（Lac）、三氟乙酸根（TFA）、氯乙酸根（ClA）、三氯乙酸根（TClA）、3-氯丙酸根（3-ClP）、4-氯丁酸根（4-ClB）和扁桃酸根（Man），以研究它们的抗菌活性以及从受损纸质文物中去除真菌和细菌的潜在应用。从受损书籍的特定色素沉着区域分离出的十种丝状真菌菌株：sp.、sp.、sp.、、sp.、、、八种革兰氏阳性和革兰氏阴性ATCC细菌菌株：、、、、、、、和两种酵母菌株：和用于本研究。结果表明，所选离子液体的抗菌活性受阴离子结构中尺寸和特定官能团的显著影响。这些事实为设计对特定细菌、霉菌和酵母菌株具有强抑制性能的新型离子液体开辟了可能性。本研究中观察到的显著抗菌性能表明，所研究的质子离子液体在纸质艺术品和文物清洁与保护方面可能具有潜在应用，从而取代对人类和环境有毒的传统溶剂和有机物质。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/e1e4d057a76a/c9ra03067k-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/9e9493138b34/c9ra03067k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/156cc06f16da/c9ra03067k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/d8cdda5da8fd/c9ra03067k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/3db5fa08f2a7/c9ra03067k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/85620b9ffe7e/c9ra03067k-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/e1e4d057a76a/c9ra03067k-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/9e9493138b34/c9ra03067k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/156cc06f16da/c9ra03067k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/d8cdda5da8fd/c9ra03067k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/3db5fa08f2a7/c9ra03067k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/85620b9ffe7e/c9ra03067k-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe9e/9064666/e1e4d057a76a/c9ra03067k-f6.jpg

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