Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts, 02139, USA.
Sci Rep. 2018 Jan 11;8(1):540. doi: 10.1038/s41598-017-18955-x.
Vapor condensation is routinely used as an effective means of transferring heat or separating fluids. Dropwise condensation, where discrete droplets form on the condenser surface, offers a potential improvement in heat transfer of up to an order of magnitude compared to filmwise condensation, where a liquid film covers the surface. Low surface tension fluid condensates such as hydrocarbons pose a unique challenge since typical hydrophobic condenser coatings used to promote dropwise condensation of water often do not repel fluids with lower surface tensions. Recent work has shown that lubricant infused surfaces (LIS) can promote droplet formation of hydrocarbons. In this work, we confirm the effectiveness of LIS in promoting dropwise condensation by providing experimental measurements of heat transfer performance during hydrocarbon condensation on a LIS, which enhances heat transfer by ≈450% compared to an uncoated surface. We also explored improvement through removal of noncondensable gases and highlighted a failure mechanism whereby shedding droplets depleted the lubricant over time. Enhanced condensation heat transfer for low surface tension fluids on LIS presents the opportunity for significant energy savings in natural gas processing as well as improvements in thermal management, heating and cooling, and power generation.
蒸汽冷凝通常被用作一种有效的传热或分离流体的手段。在滴状冷凝中,离散的液滴在冷凝器表面形成,与膜状冷凝相比,传热效率可提高一个数量级,在膜状冷凝中,液体薄膜覆盖在表面上。低表面张力的流体冷凝物(如碳氢化合物)带来了独特的挑战,因为用于促进水的滴状冷凝的典型疏水性冷凝器涂层通常不排斥表面张力较低的流体。最近的工作表明,润滑剂注入表面(LIS)可以促进碳氢化合物的液滴形成。在这项工作中,我们通过提供在 LIS 上进行碳氢化合物冷凝时的传热性能的实验测量来证实 LIS 促进滴状冷凝的有效性,与未涂层的表面相比,LIS 增强了传热,提高了约 450%。我们还通过去除不凝性气体来探索改进,并强调了一种失效机制,即随着时间的推移,液滴的脱落会耗尽润滑剂。在 LIS 上进行低表面张力流体的冷凝可以为天然气处理带来显著的节能机会,并改善热管理、加热和冷却以及发电。