i3N/CENIMAT, Department of Materials Science, Faculty of Science and Technology, Universidade NOVA de Lisboa, Campus de Caparica, 2829-516, Caparica, Portugal.
Área Departamental de Física, Instituto Superior de Engenharia de Lisboa, Instituto Politécnico de Lisboa, 1959-007, Lisbon, Portugal.
Adv Mater. 2018 May;30(19):e1703655. doi: 10.1002/adma.201703655. Epub 2018 Jan 15.
Nature has been producing cellulose since long before man walked the surface of the earth. Millions of years of natural design and testing have resulted in cellulose-based structures that are an inspiration for the production of synthetic materials based on cellulose with properties that can mimic natural designs, functions, and properties. Here, five sections describe cellulose-based materials with characteristics that are inspired by gratings that exist on the petals of the plants, structurally colored materials, helical filaments produced by plants, water-responsive materials in plants, and environmental stimuli-responsive tissues found in insects and plants. The synthetic cellulose-based materials described herein are in the form of fibers and films. Fascinating multifunctional materials are prepared from cellulose-based liquid crystals and from composite cellulosic materials that combine functionality with structural performance. Future and recent applications are outlined.
大自然早在人类在地球表面行走之前就一直在生产纤维素。数百万年的自然设计和测试,造就了基于纤维素的结构,为生产基于纤维素的合成材料提供了灵感,这些材料具有模仿自然设计、功能和特性的特性。在这里,五个部分描述了基于纤维素的材料,这些材料的特性受到了植物花瓣上的光栅、结构色材料、植物产生的螺旋丝、植物中的水响应材料以及昆虫和植物中发现的环境刺激响应组织的启发。本文所描述的合成纤维素基材料呈纤维和薄膜形式。基于纤维素的液晶和将功能与结构性能相结合的复合纤维素材料可制备出有趣的多功能材料。概述了未来和近期的应用。