机械化学激活铁氰络合物：一种前生物影响情景，用于合成α-氨基酸衍生物。
Mechanochemical Activation of Iron Cyano Complexes: A Prebiotic Impact Scenario for the Synthesis of α-Amino Acid Derivatives.
机构信息
Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.
Dipartimento di Scienze Chimiche e Geologiche, Università degli Studi di Cagliari, Cittadella Universitaria, SS 554 bivio per Sestu, 09028, Monserrato (CA), Italy.
出版信息
Angew Chem Int Ed Engl. 2018 Feb 23;57(9):2423-2426. doi: 10.1002/anie.201713109. Epub 2018 Feb 5.
Mechanochemical activation of iron cyano complexes by ball milling results in the formation of HCN, which can be trapped and incorporated into α-aminonitriles. This prebiotic impact scenario can be extended by mechanochemically transforming the resulting α-aminonitriles into α-amino amides using a chemical route related to early Earth conditions.
通过球磨机械化学激活铁氰络合物会导致 HCN 的形成，HCN 可以被捕获并掺入到α-氨基腈中。通过使用与早期地球条件相关的化学途径，将机械化学转化得到的α-氨基腈进一步转化为α-氨基酰胺，这种前生物影响场景可以得到扩展。
Zotero 插件