Key Laboratory of Chemical Biology of Jiangxi Province, College of Chemistry and Chemical Engineering, Jiangxi Normal University , Nanchang 330022, P. R. China.
J Org Chem. 2018 Feb 16;83(4):2389-2394. doi: 10.1021/acs.joc.7b02926. Epub 2018 Feb 2.
A highly efficient palladium-catalyzed oxidative cross-coupling of arylhydrazines and arenethiols with molecular oxygen as the sole oxidant to afford unsymmetrical diaryl sulfides has been developed. The only byproducts are nitrogen and water. A broad range of functional groups, even the reactive iodides, are tolerated and thus offer the opportunity for further functionalization.
发展了一种高效的钯催化的芳基腙和芳硫醇与分子氧的氧化交叉偶联反应，以提供不对称二芳基硫化物。唯一的副产物是氮气和水。该反应具有广泛的官能团容忍性，甚至包括反应性碘化物，从而为进一步的官能团化提供了机会。
