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芳基肼:交叉偶联反应中新型且通用的亲电试剂

Arylhydrazines: novel and versatile electrophilic partners in cross-coupling reactions.

作者信息

Hosseinian Akram, Mohammadi Robab, Ahmadi Sheida, Monfared Aazam, Rahmani Zahra

机构信息

School of Engineering Science, College of Engineering, University of Tehran P. O. Box 11365-4563 Tehran Iran

Department of Chemistry, Payame Noor University P. O. Box 19395-3697 Tehran Iran.

出版信息

RSC Adv. 2018 Oct 1;8(59):33828-33844. doi: 10.1039/c8ra06423g. eCollection 2018 Sep 28.

DOI:10.1039/c8ra06423g
PMID:35548837
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9086722/
Abstract

Arylhydrazines are extremely valuable compounds in organic chemistry that are widely used for the synthesis of a variety of biologically active molecules such as indoles, indazoles, pyrazoles, aryltriazoles, β-lactams and quinazolines. These compounds have also been widely utilized as arylation agents in oxidative cross-coupling reactions. In this review, we will highlight the most important explorations and developments in the carbon-carbon and carbon-heteroatom (nitrogen, phosphorus, sulfur, and selenium) cross-coupling of arylhydrazines. The literature has been surveyed from 2001 to June 2018.

摘要

芳基肼是有机化学中极具价值的化合物,广泛用于合成多种生物活性分子,如吲哚、吲唑、吡唑、芳基三唑、β-内酰胺和喹唑啉。这些化合物也被广泛用作氧化交叉偶联反应中的芳基化试剂。在本综述中,我们将重点介绍芳基肼在碳-碳和碳-杂原子(氮、磷、硫和硒)交叉偶联方面最重要的探索和进展。我们对2001年至2018年6月的文献进行了调研。

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Org Biomol Chem. 2018 Jan 17;16(3):444-451. doi: 10.1039/c7ob01929g.
10
Transition-Metal-Free and Oxidant-Free Cross-Coupling of Arylhydrazines with Disulfides: Base-Promoted Synthesis of Unsymmetrical Aryl Sulfides.无过渡金属和氧化剂参与的芳基腙与二硫化物的交叉偶联:碱促进的不对称芳基硫醚合成。
J Org Chem. 2017 Jul 7;82(13):6647-6655. doi: 10.1021/acs.joc.7b00767. Epub 2017 Jun 23.