Paris Descartes University, Sorbonne Paris Cité, Faculté des Sciences Pharmaceutiques et Biologiques, Unité CNRS UMR 8638 COMÈTE, 4 Avenue de l'observatoire, 75270 Paris Cedex 06, France.
Nat Prod Rep. 2018 Jan 25;35(1):105-124. doi: 10.1039/c7np00048k.
Covering: 2002 to August 2017.This review highlights recent RCM reactions towards the synthesis of sterically congested natural products. It offers an insight into various synthetic targets and approaches and provides information on the evolution of catalysts as powerful tools enabling the use of increasingly challenging diene precursors.
2002 年至 2017 年 8 月。本文重点介绍了最近关于 RCM 反应在合成空间位阻较大的天然产物方面的研究进展。文中介绍了各种合成目标和方法，并提供了有关催化剂发展的信息，这些催化剂是实现越来越具有挑战性的二烯前体应用的有力工具。
