镍催化 CO 与 1,3-二烯的位点选择性二羧化反应。
Ni-Catalyzed Site-Selective Dicarboxylation of 1,3-Dienes with CO.
机构信息
Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology , Av. Països Catalans 16, 43007 Tarragona, Spain.
ICREA , Passeig Lluïs Companys, 23, 08010 Barcelona, Spain.
出版信息
J Am Chem Soc. 2018 Feb 14;140(6):2050-2053. doi: 10.1021/jacs.7b13220. Epub 2018 Feb 1.
PMID:29376353
Abstract
A site-selective catalytic incorporation of multiple CO molecules into 1,3-dienes en route to adipic acids is described. This protocol is characterized by its mild conditions, excellent chemo- and regioselectivity and ease of execution under CO (1 atm), including the use of bulk butadiene and/or isoprene feedstocks.
摘要
本文描述了一种在温和条件下，通过 1,3-二烯的位点选择性催化，将多个 CO 分子高效地转化为己二酸的方法。该方法具有良好的化学和区域选择性，在 1 个大气压的 CO 条件下操作简便，包括使用丁二烯和/或异戊二烯等大宗原料。
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