BRGM, F-45060 Orléans Cedex 2, France.
BRGM, F-45060 Orléans Cedex 2, France.
Sci Total Environ. 2018 Jun 1;626:754-761. doi: 10.1016/j.scitotenv.2018.01.118. Epub 2018 Feb 19.
One of the goals of the French national campaign called "Etablissements Sensibles (Sensitive Establishments)" is to evaluate indoor air degradation in schools because of vapor intrusion of volatile compounds from soil gases towards the indoor air, related to the presence of former industrial sites on or near the establishment. During this campaign, as recommended by the United States of Environmental Protection Agency (US EPA), indoor air quality was evaluated from soil gas concentrations using generic attenuation factors, and extra investigations into soil gases and indoor air were performed when the estimated values exceeded target indoor air concentrations. This study exploits matched data on subsurface soil gases and indoor air that came from the "Sensitive Establishments" campaign. It aims to consolidate and refine the use of attenuation factors as a function of environmental variables acquired routinely during environmental assessments. We have been able to select the measured environmental variables that have the most influence on vapor intrusion using Principal Components Analysis and hypotheses tests. Since the collected data are mainly related to weak sources (only 15% schools required risk management measures related to vapor intrusion), halogenated volatile organic compounds (HVOC) were selected as tracer compounds for vapor intrusion for this study. This choice enables the exclusion or minimization of background sources contributions. From the results we have calculated the descriptive statistics of the attenuation factors distribution for the subslab-to-indoor air pathway and refined the attenuation factors for this pathway through an easily obtained parameter, building age. Qualitative comparison of attenuation factors according to the building age shows that attenuation factors observed for building less than 50 years are lower than attenuation factors for buildings 50 years old and above. These results show the utility of creating databases for consolidating and refining attenuation factors and therefore improving their use.
法国“敏感场所(Sensitive Establishments)”全国运动的目标之一是评估学校室内空气的恶化情况,原因是土壤气体中的挥发性化合物通过蒸气侵入室内空气,这与场所内或附近存在以前的工业场所有关。在这场运动中,根据美国环境保护署(US EPA)的建议,使用通用衰减因子从土壤气体浓度评估室内空气质量,并在估计值超过目标室内空气浓度时对土壤气体和室内空气进行额外调查。本研究利用来自“敏感场所”运动的地下土壤气体和室内空气的匹配数据。它旨在整合和完善衰减因子的使用,作为在环境评估中常规获取的环境变量的函数。我们已经能够使用主成分分析和假设检验选择对蒸气侵入影响最大的测量环境变量。由于收集的数据主要与弱源有关(只有 15%的学校需要与蒸气侵入有关的风险管理措施),因此选择卤代挥发性有机化合物(HVOC)作为蒸气侵入的示踪化合物。这种选择可以排除或最小化背景源的贡献。从结果中,我们计算了亚底层到室内空气途径衰减因子分布的描述性统计数据,并通过一个易于获得的参数(建筑物年龄)对该途径的衰减因子进行了细化。根据建筑物年龄对衰减因子的定性比较表明,小于 50 年的建筑物的衰减因子低于 50 年以上建筑物的衰减因子。这些结果表明,创建数据库对于整合和细化衰减因子并因此提高其使用效果非常有用。