Band Alan, Donohue Matthew P, Epel Boris, Madhu Shraeya, Szalai Veronika A
Center for Nanoscale Science and Technology, National Institute of Standards and Technology, Gaithersburg, MD 20899, United States.
Center for Nanoscale Science and Technology, National Institute of Standards and Technology, Gaithersburg, MD 20899, United States; Maryland NanoCenter, University of Maryland, College Park, MD 20742, United States.
J Magn Reson. 2018 Mar;288:28-36. doi: 10.1016/j.jmr.2018.01.010. Epub 2018 Feb 2.
We present a 34 GHz continuous wave (CW)/pulsed electron paramagnetic resonance (EPR) spectrometer capable of pulse-shaping that is based on a versatile microwave bridge design. The bridge radio frequency (RF)-in/RF-out design (500 MHz to 1 GHz input/output passband, 500 MHz instantaneous input/output bandwidth) creates a flexible platform with which to compare a variety of excitation and detection methods utilizing commercially available equipment external to the bridge. We use three sources of RF input to implement typical functions associated with CW and pulse EPR spectroscopic measurements. The bridge output is processed via high speed digitizer and an in-phase/quadrature (I/Q) demodulator for pulsed work or sent to a wideband, high dynamic range log detector for CW. Combining this bridge with additional commercial hardware and new acquisition and control electronics, we have designed and constructed an adaptable EPR spectrometer that builds upon previous work in the literature and is functionally comparable to other available systems.
我们展示了一种基于通用微波桥设计的、能够进行脉冲整形的34吉赫兹连续波(CW)/脉冲电子顺磁共振(EPR)光谱仪。该桥的射频(RF)输入/输出设计(500兆赫兹至1吉赫兹输入/输出通带,500兆赫兹瞬时输入/输出带宽)创建了一个灵活的平台,利用该平台可以使用桥外部的商用设备比较各种激发和检测方法。我们使用三种射频输入源来实现与连续波和脉冲EPR光谱测量相关的典型功能。对于脉冲工作,桥输出通过高速数字化仪和同相/正交(I/Q)解调器进行处理,对于连续波则发送到宽带、高动态范围对数检测器。将此桥与额外的商用硬件以及新的采集和控制电子设备相结合,我们设计并构建了一种适应性强的EPR光谱仪,该光谱仪基于文献中先前的工作,在功能上与其他现有系统相当。