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一种基于化学沉淀法制备的Cr₂O₃-SnO₂异质结纳米复合材料的高灵敏度异丙醇蒸汽传感器。

A High Sensitivity Isopropanol Vapor Sensor Based on Cr₂O₃-SnO₂ Heterojunction Nanocomposites via Chemical Precipitation Route.

作者信息

Jawaher K Rackesh, Indirajith R, Krishnan S, Robert R, Pasha S K Khadheer, Deshmukh Kalim, Sastikumar D, Das S Jerome

机构信息

Department of Physics, B.S. Abdur Rahman Crescent University, Chennai 600048, Tamil Nadu, India.

Department of Physics, Ramakrishna Mission Vivekananda College (Autonomous), Chennai 600004, India.

出版信息

J Nanosci Nanotechnol. 2018 Aug 1;18(8):5454-5460. doi: 10.1166/jnn.2018.15396.

Abstract

Cr2O3-SnO2 heterojunction nanocomposites were prepared via chemical precipitation method. The prepared samples were characterized by X-ray diffraction (XRD), Transmission electron microscopy (TEM), UV-Vis diffuse reflectance spectra and Field Emission Electron Microscopy (FESEM). The XRD spectrum confirms the presence of both tetragonal rutile SnO2 and rhombohedral corundum Cr2O3 structure. Further investigation into the gas sensing performances of the prepared Cr2O3-SnO2 nanocomposites exhibited an enhanced sensitivity towards VOPs such as isopropanol, acetone, ethanol and formaldehyde. Especially, isopropanol vapor sensor shows excellent sensitivity at an operating temperature of 100 °C. The highest sensitivity for Cr2O3-SnO2 heterojunction nanocomposites indicate that these materials can be a good candidate for the production of high-performance isopropanol sensors.

摘要

采用化学沉淀法制备了Cr2O3-SnO2异质结纳米复合材料。通过X射线衍射(XRD)、透射电子显微镜(TEM)、紫外-可见漫反射光谱和场发射电子显微镜(FESEM)对制备的样品进行了表征。XRD光谱证实了四方金红石型SnO2和菱面体刚玉型Cr2O3结构的存在。对制备的Cr2O3-SnO2纳米复合材料的气敏性能进行的进一步研究表明,其对异丙醇、丙酮、乙醇和甲醛等挥发性有机化合物(VOPs)具有增强的灵敏度。特别是,异丙醇气体传感器在100℃的工作温度下表现出优异的灵敏度。Cr2O3-SnO2异质结纳米复合材料的最高灵敏度表明,这些材料可成为生产高性能异丙醇传感器的良好候选材料。

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