硫原子导向的钌催化C(sp)-H键的氢同位素交换反应
Ruthenium-catalyzed hydrogen isotope exchange of C(sp)-H bonds directed by a sulfur atom.
作者信息
Gao Longhui, Perato Serge, Garcia-Argote Sébastien, Taglang Céline, Martínez-Prieto Luis Miguel, Chollet Céline, Buisson David-Alexandre, Dauvois Vincent, Lesot Philippe, Chaudret Bruno, Rousseau Bernard, Feuillastre Sophie, Pieters Grégory
机构信息
SCBM, CEA, Université Paris Saclay, F-91191, Gif-sur-Yvette, France.
LPCNO, Laboratoire de Physique et Chimie de Nano-Objets, UMR 5215 INSA-CNRS-UPS, Institut National des Sciences Appliquées, 135, Avenue de Rangueil, 31077 Toulouse, France.
出版信息
Chem Commun (Camb). 2018 Mar 25;54(24):2986-2989. doi: 10.1039/c8cc00653a. Epub 2018 Mar 5.
We present here the first example of C(sp)-H activation directed by a sulfur atom. Based on this transformation catalyzed by Ru/C, we have developed a hydrogen isotope exchange reaction for the deuterium and tritium labelling of thioether substructures in complex molecules.
我们在此展示了由硫原子导向的C(sp) - H活化的首个实例。基于钌/碳催化的这种转化，我们开发了一种用于复杂分子中硫醚亚结构氘代和氚代标记的氢同位素交换反应。
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