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一种双相镁锂合金的动态再结晶行为及耐蚀性

Dynamic Recrystallization Behavior and Corrosion Resistance of a Dual-Phase Mg-Li Alloy.

作者信息

Liu Gang, Xie Wen, Wei Guobing, Yang Yan, Liu Junwei, Xu Tiancai, Xie Weidong, Peng Xiaodong

机构信息

College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China.

National Engineering Research Center for Magnesium Alloys, Chongqing 400044, China.

出版信息

Materials (Basel). 2018 Mar 9;11(3):408. doi: 10.3390/ma11030408.

DOI:10.3390/ma11030408
PMID:29522473
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5872987/
Abstract

The hot deformation and dynamic recrystallization behavior of the dual-phase Mg-9Li-3Al-2Sr-2Y alloy had been investigated using a compression test. The typical dual-phase structure was observed, and average of grain size of as-homogenized alloy is about 110 µm. It mainly contains β-Li, α-Mg, Al₄Sr and Al₂Y phases. The dynamic recrystallization (DRX) kinetic was established based on an Avrami type equation. The onset of the DRX process occurred before the peak of the stress-strain flow curves. It shows that the DRX volume fraction increases with increasing deformation temperature or decreasing strain rate. The microstructure evolution during the hot compression at various temperatures and strain rates had been investigated. The DRX grain size became larger with the increasing testing temperature or decreasing strain rate because the higher temperature or lower strain rate can improve the migration of DRX grain boundaries. The fully recrystallized microstructure can be achieved in a small strain due to the dispersed island-shape α-Mg phases, continuous the Al₄Sr phases and spheroidal Al₂Y particles, which can accelerate the nucleation. The continuous Al₄Sr phases along the grain boundaries are very helpful for enhancing the corrosion resistance of the duplex structured Mg-Li alloy, which can prevent the pitting corrosion and filiform corrosion.

摘要

采用压缩试验研究了双相Mg-9Li-3Al-2Sr-2Y合金的热变形和动态再结晶行为。观察到典型的双相组织,均匀化处理后的合金平均晶粒尺寸约为110μm。它主要包含β-Li、α-Mg、Al₄Sr和Al₂Y相。基于阿弗拉米型方程建立了动态再结晶(DRX)动力学。DRX过程的起始点出现在应力-应变流动曲线的峰值之前。结果表明,DRX体积分数随变形温度的升高或应变速率的降低而增加。研究了不同温度和应变速率下热压缩过程中的微观组织演变。由于较高的温度或较低的应变速率可以改善DRX晶界的迁移,DRX晶粒尺寸随试验温度的升高或应变速率的降低而增大。由于弥散分布的岛状α-Mg相、连续的Al₄Sr相和球状Al₂Y颗粒能够促进形核,在小应变下即可获得完全再结晶的微观组织。沿晶界的连续Al₄Sr相对于提高双相结构Mg-Li合金的耐蚀性非常有帮助,能够防止点蚀和丝状腐蚀。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f575/5872987/95be5f8f9da2/materials-11-00408-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f575/5872987/95be5f8f9da2/materials-11-00408-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f575/5872987/7e6f1b639c5d/materials-11-00408-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f575/5872987/80bf36514346/materials-11-00408-g008.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f575/5872987/95be5f8f9da2/materials-11-00408-g011.jpg

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