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光敏石墨烯 P-N 结晶体管和三元反相器。

Photosensitive Graphene P-N Junction Transistors and Ternary Inverters.

出版信息

ACS Appl Mater Interfaces. 2018 Apr 18;10(15):12897-12903. doi: 10.1021/acsami.8b00483. Epub 2018 Apr 3.

Abstract

We investigate the electric transport in a graphene-organic dye hybrid and the formation of p-n junctions. In the conventional approach, graphene p-n junctions are produced by using multiple electrostatic gates or local chemical doping, which produce different types of carriers in graphene. Instead of using multiple gates or typical chemical doping, a different approach to fabricate p-n junctions is proposed. The approach is based on optical gating of photosensitive dye molecules; this method can produce a well-defined sharp junction. The potential difference in the proposed p-n junction can be controlled by varying the optical power of incident light. A theoretical calculation based on the effective medium theory is performed to thoroughly explain the experimental data. The characteristic transport behavior of the photosensitive graphene p-n junction opens new possibilities for graphene-based devices, and we use the results to fabricate ternary inverters. Our strategy of building a simple hybrid p-n junction can further offer many opportunities in the near future of tuning it for other optoelectronic functionalities.

摘要

我们研究了石墨烯-有机染料杂化材料中的电输运和 p-n 结的形成。在传统方法中,通过使用多个静电门或局部化学掺杂来产生石墨烯 p-n 结,这会在石墨烯中产生不同类型的载流子。为了避免使用多个门或典型的化学掺杂,我们提出了一种制造 p-n 结的不同方法。该方法基于对光敏染料分子的光门控,这种方法可以产生明确定义的锐利结。通过改变入射光的光功率,可以控制所提出的 p-n 结中的电势差。基于有效媒质理论的理论计算对实验数据进行了彻底的解释。光敏石墨烯 p-n 结的特征传输行为为基于石墨烯的器件开辟了新的可能性,我们使用该结果制造了三进制逆变器。我们构建简单混合 p-n 结的策略在不久的将来可以为其他光电功能的调整提供更多的机会。

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