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高效可靠的透明电磁屏蔽膜。

Highly Efficient and Reliable Transparent Electromagnetic Interference Shielding Film.

机构信息

Department of Materials Science and Engineering, Henry Samueli School of Engineering and Applied Science , University of California , Los Angeles , California 90095 , United States.

出版信息

ACS Appl Mater Interfaces. 2018 Apr 11;10(14):11941-11949. doi: 10.1021/acsami.8b00492. Epub 2018 Mar 28.

Abstract

Electromagnetic protection in optoelectronic instruments such as optical windows and electronic displays is challenging because of the essential requirements of a high optical transmittance and an electromagnetic interference (EMI) shielding effectiveness (SE). Herein, we demonstrate the creation of an efficient transparent EMI shielding film that is composed of calcium alginate (CA), silver nanowires (AgNWs), and polyurethane (PU), via a facile and low-cost Mayer-rod coating method. The CA/AgNW/PU film with a high optical transmittance of 92% achieves an EMI SE of 20.7 dB, which meets the requirements for commercial shielding applications. A superior EMI SE of 31.3 dB could be achieved, whereas the transparent film still maintains a transmittance of 81%. The integrated efficient EMI SE and high transmittance are superior to those of most previously reported transparent EMI shielding materials. Moreover, our transparent films exhibit a highly reliable shielding ability in a complex service environment, with 98 and 96% EMI SE retentions even after 30 min of ultrasound treatment and 5000 bending cycles (1.5 mm radius), respectively. The comprehensive performance that is associated with the facile fabrication strategy imparts the CA/AgNW/PU film with great potential as an optimized EMI shielding material in emerging optoelectronic devices, such as flexible solar cells, displays, and touch panels.

摘要

光电仪器(如光学窗口和电子显示器)中的电磁保护具有挑战性,因为其必须满足高透光率和电磁干扰(EMI)屏蔽效能(SE)的基本要求。在此,我们通过简便且低成本的 Mayer 棒涂层方法,展示了一种由海藻酸钠(CA)、银纳米线(AgNWs)和聚氨酯(PU)组成的高效透明 EMI 屏蔽膜的制备。具有 92%高透光率的 CA/AgNW/PU 膜实现了 20.7 dB 的 EMI SE,满足商业屏蔽应用的要求。此外,还可以实现卓越的 EMI SE 为 31.3 dB,同时透明膜仍保持 81%的透光率。综合高效 EMI SE 和高透光率优于大多数先前报道的透明 EMI 屏蔽材料。此外,我们的透明膜在复杂的使用环境中表现出高度可靠的屏蔽能力,即使经过 30 分钟的超声处理和 5000 次弯曲循环(半径为 1.5 毫米)后,仍分别保持 98%和 96%的 EMI SE 保留率。与简便制造策略相关的综合性能使 CA/AgNW/PU 膜在新兴的光电设备(如柔性太阳能电池、显示器和触摸面板)中的 EMI 屏蔽材料方面具有巨大潜力。

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