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Org Lett. 2018 Apr 6;20(7):1987-1990. doi: 10.1021/acs.orglett.8b00540. Epub 2018 Mar 20.
A continuous mesofluidic process has been developed for benzylic C-H oxidation with moderate to good yields using a photocatalyst (riboflavin tetraacetate, RFT) activated by a UV lamp and an iron additive [Fe(ClO)] via incorporation of singlet oxygen (O) for the direct formation of oxidized C═O or CH-OH compounds.
已开发出一种连续的中观流处理方法，用于苄基 C-H 氧化，使用光催化剂（核黄素四乙酸酯，RFT）在紫外线灯和铁添加剂[Fe（ClO）]的作用下激活，通过掺入单线态氧（O）来直接形成氧化的 C═O 或 CH-OH 化合物，产率中等至良好。
