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手性催化剂固载于非手性聚合物上:聚合物载体对催化剂性能的影响。

Chiral catalysts immobilized on achiral polymers: effect of the polymer support on the performance of the catalyst.

机构信息

Department of Inorganic and Organic Chemistry, University Jaume I, Avda Sos Baynat s/n, E-12071, Castellón, Spain.

出版信息

Chem Soc Rev. 2018 Apr 23;47(8):2722-2771. doi: 10.1039/c7cs00734e.

DOI:10.1039/c7cs00734e
PMID:29577129
Abstract

Positive effects of the polymeric support on the performance of supported chiral catalysts, in terms of activity, stability and selectivity-enantioselectivity, have been reported when the support is properly selected and optimized opening the way to the design of more efficient catalytic systems.

摘要

当选择和优化支撑体时,高分子支撑体对负载手性催化剂的性能(活性、稳定性和选择性-对映选择性)具有积极影响,为设计更高效的催化体系开辟了道路。

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