Shin Jong Won, Jeong Ah Rim, Jeoung Sungeun, Moon Hoi Ri, Komatsumaru Yuki, Hayami Shinya, Moon Dohyun, Min Kil Sik
Department of Chemistry, Kyungpook National University, Daegu 41566, Republic of Korea.
Chem Commun (Camb). 2018 Apr 24;54(34):4262-4265. doi: 10.1039/c8cc00678d.
We report a three-dimensional Fe(ii) porous coordination polymer that exhibits a spin crossover temperature change following CO2 sorption (though not N2 sorption). Furthermore, single crystals of the desolvated polymer with CO2 molecules at three different temperatures were characterised by X-ray crystallography.
我们报道了一种三维铁（II）多孔配位聚合物，该聚合物在吸附二氧化碳后（但不吸附氮气）会出现自旋交叉温度变化。此外，通过X射线晶体学对在三个不同温度下含有二氧化碳分子的去溶剂化聚合物单晶进行了表征。
