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在极低过氧化物水平下的无铂微引擎。

Pt-Free microengines at extremely low peroxide levels.

机构信息

Department of Chemical Engineering, Curtin University, GPO Box U1987, Perth, Western Australia 6845, Australia.

Key Lab of Advance Materials Technology of Educational Department Liaoning Province, Shenyang University, Shenyang, 110044, China.

出版信息

Chem Commun (Camb). 2018 May 3;54(37):4653-4656. doi: 10.1039/c8cc01548a.

Abstract

Herein, we demonstrate that iron oxide modified MnO2 (FeOx-MnO2) catalyzed micromotors can be fabricated via electrochemical co-reduction and exhibit exceptional high performance at an extremely low hydrogen peroxide (H2O2) fuel concentration. We observed that graphene/FeOx-MnO2 microtubes could show motion behaviors at fuel concentration as low as 0.03% H2O2, which is nearly one order of magnitude lower than Pt-based micromotors (normally at above 0.2% H2O2). Moreover, the micromotors exhibit higher speeds than any other reported catalytic micro/nanomotors (MNMs) at low peroxide levels. The FeOx-MnO2 systems are better catalytic MNMs, due to their excellent catalytic activity, easy fabrication, robust structure and movement, as well as low-cost, biocompatible and abundance nature, showing great potential for future applications.

摘要

在此,我们证明了通过电化学共还原可以制备氧化铁修饰的 MnO2(FeOx-MnO2)催化剂,并在极低浓度的过氧化氢(H2O2)燃料下表现出非凡的高性能。我们观察到,石墨烯/FeOx-MnO2 微管在燃料浓度低至 0.03% H2O2 时就可以表现出运动行为,这比基于 Pt 的微马达(通常在 0.2% H2O2 以上)低了近一个数量级。此外,在低过氧化物水平下,这些微马达的速度比任何其他报道的催化微纳米马达(MNMs)都要高。FeOx-MnO2 体系是更好的催化 MNMs,因为它们具有优异的催化活性、易于制造、坚固的结构和运动性,以及低成本、生物相容性和丰富的特性,在未来的应用中具有巨大的潜力。

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