Xing Lei, Dong Yidi, Hu Fang, Wu Xiang, Umar Ahmad
School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China.
Dalton Trans. 2018 Apr 24;47(16):5687-5694. doi: 10.1039/c8dt00750k.
Herein, we report a simple and facile sequential hydrothermal process for the synthesis of Co3O4 nanowire@NiO nanosheet arrays (CNAs). The as-synthesized CNAs were characterized in detail using various analytical techniques, which confirmed the high crystallinity, purity, and high-density growth of these nanomaterials. From an application point of view, the as-synthesized CNAs were directly used as supercapacitor electrodes, revealing a specific capacitance of up to 2018 mF cm-2 at a current density of 2 mA cm-2. Furthermore, a flexible asymmetric supercapacitor was fabricated using the as-synthesized CNAs as the anode and activated carbon as the cathode, which revealed a specific capacitance of 134.6 mF cm-2 at a current density of 2 mA cm-2. In addition, the supercapacitor showed excellent capacity retention of 73.5% after 10 000 cycles at a current density of 10 mA cm-2.
在此,我们报道了一种用于合成Co3O4纳米线@NiO纳米片阵列(CNAs)的简单且便捷的连续水热法。使用各种分析技术对合成的CNAs进行了详细表征,证实了这些纳米材料具有高结晶度、纯度和高密度生长。从应用角度来看,合成的CNAs直接用作超级电容器电极,在电流密度为2 mA cm-2时,比电容高达2018 mF cm-2。此外,以合成的CNAs为阳极、活性炭为阴极制备了一种柔性不对称超级电容器,在电流密度为2 mA cm-2时,其比电容为134.6 mF cm-2。此外,该超级电容器在电流密度为10 mA cm-2下循环10000次后,容量保持率高达73.5%。