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用于高性能不对称超级电容器的氧化钴纳米线@氧化镍纳米片阵列

CoO nanowire@NiO nanosheet arrays for high performance asymmetric supercapacitors.

作者信息

Xing Lei, Dong Yidi, Hu Fang, Wu Xiang, Umar Ahmad

机构信息

School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China.

出版信息

Dalton Trans. 2018 Apr 24;47(16):5687-5694. doi: 10.1039/c8dt00750k.

Abstract

Herein, we report a simple and facile sequential hydrothermal process for the synthesis of Co3O4 nanowire@NiO nanosheet arrays (CNAs). The as-synthesized CNAs were characterized in detail using various analytical techniques, which confirmed the high crystallinity, purity, and high-density growth of these nanomaterials. From an application point of view, the as-synthesized CNAs were directly used as supercapacitor electrodes, revealing a specific capacitance of up to 2018 mF cm-2 at a current density of 2 mA cm-2. Furthermore, a flexible asymmetric supercapacitor was fabricated using the as-synthesized CNAs as the anode and activated carbon as the cathode, which revealed a specific capacitance of 134.6 mF cm-2 at a current density of 2 mA cm-2. In addition, the supercapacitor showed excellent capacity retention of 73.5% after 10 000 cycles at a current density of 10 mA cm-2.

摘要

在此,我们报道了一种用于合成Co3O4纳米线@NiO纳米片阵列(CNAs)的简单且便捷的连续水热法。使用各种分析技术对合成的CNAs进行了详细表征,证实了这些纳米材料具有高结晶度、纯度和高密度生长。从应用角度来看,合成的CNAs直接用作超级电容器电极,在电流密度为2 mA cm-2时,比电容高达2018 mF cm-2。此外,以合成的CNAs为阳极、活性炭为阴极制备了一种柔性不对称超级电容器,在电流密度为2 mA cm-2时,其比电容为134.6 mF cm-2。此外,该超级电容器在电流密度为10 mA cm-2下循环10000次后,容量保持率高达73.5%。

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