Qaroush Abdussalam K, Alshamaly Hiba S, Alazzeh Shrouq S, Abeskhron Ream H, Assaf Khaleel I, Eftaiha Ala'a F
Department of Chemistry , Faculty of Science , The University of Jordan , Amman 11942 , Jordan . Email:
Department of Chemistry , The Hashemite University , P. O. Box 150459 , Zarqa 13115 , Jordan . Email:
Chem Sci. 2018 Jan 5;9(5):1088-1100. doi: 10.1039/c7sc04706a. eCollection 2018 Feb 7.
The economic viability of eco-friendly and renewable materials promotes the development of an alternative technology for climate change mitigation. Investigations reported over the past few years have allowed understanding the mechanism of action for a wide spectrum of saccharides toward carbon dioxide (CO), in terms of reactivity, reversibility, stability and uptake. Exploiting bio-renewables, , inedible saccharides, to reduce the anthropogenic carbon footprint upon providing a sustainable and promising technology that is of interest to different groups of scientists, to overcome demerits associated with the current state-of-the-art aqueous amine scrubbing agents, following a "green chemistry guideline", by employing materials with properties relevant to the environment toward sustainable development. The interdisciplinary nature of research in this area provides a large body of literature that would meet the interest of the broad readership of different multidisciplinary fields. Although many reports emphasize the use of biomass in various industrial products ranging from pharmaceutics, medical preparations, soaps, textiles, cosmetics, household cleaners, and so on, to our knowledge there is no focused article that addresses the application of saccharides for CO sequestration. In this review, we highlight the recent advances on the use of oligo-, poly- and cyclic saccharides to achieve a reversible binding of CO. The future research directions are discussed to provide insight toward achieving sustainable development through implementing bio-renewables.
环保型和可再生材料的经济可行性推动了一种减缓气候变化替代技术的发展。过去几年报道的研究使人们能够从反应性、可逆性、稳定性和吸收性等方面理解多种糖类对二氧化碳（CO）的作用机制。利用生物可再生资源，即不可食用的糖类，遵循“绿色化学指南”，通过使用与环境相关的材料来实现可持续发展，从而在提供一种可持续且有前景的技术的同时，减少人为碳足迹，这一技术受到不同科学家群体的关注，以克服与当前最先进的水性胺类吸收剂相关的缺点。该领域研究的跨学科性质提供了大量文献，能满足不同多学科领域广大读者的兴趣。尽管许多报告强调了生物质在从制药、医疗制剂、肥皂、纺织品、化妆品、家用清洁剂等各种工业产品中的应用，但据我们所知，尚无专门论述糖类在CO封存方面应用的文章。在本综述中，我们重点介绍了寡糖、多糖和环状糖类在实现CO可逆结合方面的最新进展。还讨论了未来的研究方向，以便为通过实施生物可再生资源实现可持续发展提供见解。
