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评价经胶体海藻提取物功能化银纳米粒子涂层处理的棉织物的 UPF 和抗菌活性。

Evaluation of UPF and antibacterial activity of cotton fabric coated with colloidal seaweed extract functionalized silver nanoparticles.

机构信息

Bio-nanomaterials Research Lab, Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630003, Tamil Nadu, India.

Bio-nanomaterials Research Lab, Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630003, Tamil Nadu, India.

出版信息

J Photochem Photobiol B. 2018 Jun;183:75-87. doi: 10.1016/j.jphotobiol.2018.04.028. Epub 2018 Apr 18.

Abstract

In the present study, green synthesis of silver nanoparticles (AgNPs) functionalized with seaweed (Padina gymnospora) extract was investigated. Thus synthesized AgNPs were coated on cotton fabric by pad try-cure method using citric acid as a cross linking agent. The chemical linkage of colloidal AgNPs onto the cellulosic structure are characterized and confirmed by FTIR, SEM, EDX and AFM analysis. The optical, crystalline and morphological features of the functionalized AgNPs were confirmed by UV-Visible, X-ray diffraction and TEM analysis. The size of the functionalized AgNPs was found to be 2-20 nm, there by rendering the small spherical shaped particles are suitable for the biomedical applications. The surface roughness (R) of the sample was found to be 70 μm. AgNPs coated fabric getting greater UPF (UV Protection Factor) values than they compared to seaweed extracts coated and uncoated cotton fabric. The antibacterial activity of AgNPs coated fabric was investigated, getting greater inhibition effect against S. aureus (Gram positive) and E. coli (Gram negative) microbial strains. Durability of the AgNPs coating was also tested after 10 repeated washings. Then after the 10 repeated washings of AgNPs coated fabric provided the better retainable UV protection efficiency and microbial inhibitory activity results obtained as for the before washings with slight changes.

摘要

在本研究中,研究了用海藻(脊尾褐藻)提取物进行绿色合成的银纳米粒子(AgNPs)。采用柠檬酸作为交联剂,通过垫轧-固色法将合成的 AgNPs 涂覆在棉织物上。通过傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)、能谱分析(EDX)和原子力显微镜(AFM)分析,对胶体 AgNPs 与纤维素结构的化学结合进行了表征和确认。通过紫外-可见分光光度计(UV-Visible)、X 射线衍射(X-ray diffraction)和透射电子显微镜(TEM)分析,对功能化 AgNPs 的光学、结晶和形态特征进行了确认。功能化 AgNPs 的尺寸为 2-20nm,呈小的球形,适合生物医学应用。发现样品的表面粗糙度(R)为 70μm。AgNPs 涂层织物的紫外线防护因子(UPF)值比海藻提取物涂层和未涂层的棉织物都要高。研究了 AgNPs 涂层织物的抗菌活性,发现其对金黄色葡萄球菌(革兰氏阳性)和大肠杆菌(革兰氏阴性)微生物菌株具有更大的抑制作用。还测试了 AgNPs 涂层的耐用性,经过 10 次重复洗涤后。经过 10 次重复洗涤后,AgNPs 涂层织物的紫外线防护效率和微生物抑制活性保持良好,与洗涤前相比仅有轻微变化。

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