寻找对高氚酸根和高锝酸根具有选择性识别能力的受体设计：氢键与卤键。
Finding a receptor design for selective recognition of perrhenate and pertechnetate: hydrogen vs. halogen bonding.
机构信息
Institute of Chemistry, Technische Universität Chemnitz, Chemnitz, 09107, Germany.
出版信息
Chem Commun (Camb). 2018 May 8;54(38):4826-4829. doi: 10.1039/c8cc02048e.
PMID:29694469
Abstract
Receptors bearing hydrogen and halogen bond donors for recognition of perrhenate and pertechnetate were designed and studied. Acyclic hosts with N-H and C-H binding sites showed the best selectivity for TcO4- and ReO4- over spherical and more basic tetrahedral anions.
摘要
设计并研究了具有氢键和卤素键给体受体的放射性碘酸盐和锝酸盐识别受体。具有 N-H 和 C-H 结合位点的非环主体对 TcO4-和 ReO4-表现出最佳的选择性，优于球形和更碱性的四面体阴离子。
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