College of Chemistry and Molecular Engineering , Zhengzhou University , Zhengzhou 450001 , China.
Department of Chemistry and Center of Novel Functional Molecules , The Chinese University of Hong Kong , Shatin, New Territories , Hong Kong.
Inorg Chem. 2018 May 7;57(9):4828-4832. doi: 10.1021/acs.inorgchem.8b00702. Epub 2018 Apr 26.
A polyoxometalate-templated silver(I) thiolate nanocluster has been synthesized by a one-pot reaction in high yield. This novel and stable nanocluster exhibits a core-shell structure with a AgS shell and two lacunary Keggin [PWO] cores, which is fully characterized by X-ray crystallography, X-ray photoelectron spectroscopy, UV-vis, powder X-ray diffraction, and cyclic voltammetry.
一种多金属氧酸盐模板的银（I）硫醇纳米簇通过一锅反应高产率合成。这种新颖且稳定的纳米簇具有 AgS 壳和两个空穴的 Keggin [PWO] 核的核壳结构，通过 X 射线晶体学、X 射线光电子能谱、紫外-可见光谱、粉末 X 射线衍射和循环伏安法进行了全面表征。
