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[Ag(70)(PW(9)O(34))(2)((t)BuC[triple bond, length as m-dash]C)(44)(H(2)O)(2)](8+): 离子热合成包裹空缺多金属氧酸盐离子的银原子簇。

[Ag(70)(PW(9)O(34))(2)((t)BuC[triple bond, length as m-dash]C)(44)(H(2)O)(2)](8+): ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions.

机构信息

State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering Xiamen, 361005, P. R. China.

出版信息

Chem Commun (Camb). 2014 Mar 4;50(18):2353-5. doi: 10.1039/c3cc49290g. Epub 2014 Jan 21.

DOI:10.1039/c3cc49290g
PMID:24448207
Abstract

A silver alkynyl cluster containing a Ag70 shell and two lacunary PW9O34 templating ions was synthesized by an ionothermal approach. Fast core-shell electronic communication between silver(i) centers and polyoxometalates was verified via cyclic voltammetry studies in [BMIm]BF4.

摘要

一种含有 Ag70 壳和两个空缺的PW9O34模板离子的银炔基簇合物通过离子热方法合成。通过在[BMIm]BF4 中的循环伏安研究证实了银(i)中心和多金属氧酸盐之间的快速核壳电子通讯。

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