一种用于钴新晶体结构的溶液相化学方法。
A Solution-Phase Chemical Approach to a New Crystal Structure of Cobalt.
作者信息
Dinega Dmitry P, Bawendi M G
机构信息
Department of Chemistry and Center for Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge MA 02139 (USA), Fax: (+1) 617-253-7030.
出版信息
Angew Chem Int Ed Engl. 1999 Jun 14;38(12):1788-1791. doi: 10.1002/(SICI)1521-3773(19990614)38:12<1788::AID-ANIE1788>3.0.CO;2-2.
Kinetic control of crystal growth in the presence of a coordinating ligand is critical for the formation of a new structure of elemental cobalt (ε-cobalt, the unit cell with the two different types of cobalt atoms is shown), which was discovered upon analyzing the metallic powder produced by the thermal decomposition of [Co (CO) ] in solution in the presence of trioctylphosphane oxide [TOPO, Eq. (1)].
在配位配体存在的情况下，对晶体生长进行动力学控制对于形成元素钴的新结构（ε-钴，展示了具有两种不同类型钴原子的晶胞）至关重要，这是在分析在三辛基氧化膦[TOPO，式(1)]存在下，通过[Co(CO)]在溶液中的热分解产生的金属粉末时发现的。
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