金属聚电解质：将大分子结构与性质及应用相关联
Metallo-Polyelectrolytes: Correlating Macromolecular Architectures with Properties and Applications.
作者信息
Zhu Tianyu, Zhang Jiuyang, Tang Chuanbing
机构信息
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA.
School of Chemistry and Chemical Engineering, Jiangsu Hi-Tech Key Laboratory for Biomedical Research, Southeast University, 211189, Nanjing, PR China.
出版信息
Trends Chem. 2020 Mar;2(3):227-240. doi: 10.1016/j.trechm.2019.12.004. Epub 2019 Dec 27.
Since the middle of the 20th century, metallopolymers have represented a standalone subfield with a beneficial combination of functionality from inorganic metal centers and processability from the organic polymeric frameworks. Metallo-polyelectrolytes are a new class of soft materials that showcase fundamentally different properties from neutral polymers due to their intrinsically ionic behaviors. This review describes recent trends in metallo-polyelectrolytes and discusses emerging properties and challenges, as well as future directions from a perspective of macromolecular architectures. The correlations between macromolecular architectures and properties are discussed from copolymer self-assembly, metallo-enzymes for biomedical applications, metallo-peptides for catalysis, crosslinked networks, and metallogels.
自20世纪中叶以来，金属聚合物已成为一个独立的子领域，它兼具无机金属中心的功能性和有机聚合物骨架的可加工性。金属聚电解质是一类新型软材料，由于其固有的离子行为，它们展现出与中性聚合物截然不同的性质。本文综述了金属聚电解质的最新研究趋势，讨论了其新兴性质、挑战以及从大分子结构角度出发的未来发展方向。从共聚物自组装、生物医学应用的金属酶、催化用金属肽、交联网络和金属凝胶等方面讨论了大分子结构与性质之间的相关性。
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