在络合金属阳离子处多碘化物网络的模板组装：[Pd Cl ([18]aneN S )] I (I ) 和 [K([15]aneO ) ]I的合成与结构
Template Assembly of Polyiodide Networks at Complexed Metal Cations: Synthesis and Structures of [Pd Cl ([18]aneN S )] I (I ) and [K([15]aneO ) ]I.
作者信息
Blake Alexander J, Gould Robert O, Li Wan-Sheung, Lippolis Vito, Parsons Simon, Radek Christian, Schröder Martin
机构信息
Department of Chemistry, The University of Nottingham, University Park, Nottingham, NG7 2RD (UK), Fax: Int. code+(44) 115 9513563.
Department of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh EH9 3JJ (UK).
出版信息
Angew Chem Int Ed Engl. 1998 Feb 16;37(3):293-296. doi: 10.1002/(SICI)1521-3773(19980216)37:3<293::AID-ANIE293>3.0.CO;2-5.
The cations [Pd Cl L] and [KL (L = [18]aneN S , L' =[15]aneO ) have been used as templates for the synthesis of unique three-dimensional polyiodide networks. The metal cations in [Pd Cl L] I (I ) are linked into infinite chains by pairwise hydrogen bonding; the resulting cationic polymers run through channels formed by the extended polyiodide network. [KL ]I shows a three-dimensional network of puckered cubic cages of I ions whose cavities are occupied by the metal cations (section from the structure shown on the right).
阳离子[Pd Cl L]和[KL（L = [18]aneN S，L' = [15]aneO）已被用作合成独特三维聚碘化物网络的模板。[Pd Cl L] I（I）中的金属阳离子通过成对氢键连接成无限链；生成的阳离子聚合物贯穿由扩展聚碘化物网络形成的通道。[KL]I显示出由I离子组成的褶皱立方笼的三维网络，其空腔被金属阳离子占据（右侧所示结构的截面）。
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