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基于聚酰亚胺的电容式湿度传感器。

Polyimide-Based Capacitive Humidity Sensor.

机构信息

Fraunhofer EMFT, Research Institution for Microsystems and Solid State Technologies EMFT, Hansastraße 27d, D-80686 Munich, Germany.

Institute of Electronic and Sensor Materials, Technische Universität Bergakademie Freiberg, Gustav-Zeuner-Str. 3, D-09599 Freiberg, Germany.

出版信息

Sensors (Basel). 2018 May 11;18(5):1516. doi: 10.3390/s18051516.

Abstract

The development of humidity sensors with simple transduction principles attracts considerable interest by both scientific researchers and industrial companies. Capacitive humidity sensors, based on polyimide sensing material with different thickness and surface morphologies, are prepared. The surface morphology of the sensing layer is varied from flat to rough and then to nanostructure called nanograss by using an oxygen plasma etch process. The relative humidity (RH) sensor selectively responds to the presence of water vapor by a capacitance change. The interaction between polyimide and water molecules is studied by FTIR spectroscopy. The complete characterization of the prepared capacitive humidity sensor performance is realized using a gas mixing setup and an evaluation kit. A linear correlation is found between the measured capacitance and the RH level in the range of 5 to 85%. The morphology of the humidity sensing layer is revealed as an important parameter influencing the sensor performance. It is proved that a nanograss-like structure is the most effective for detecting RH, due to its rapid response and recovery times, which are comparable to or even better than the ones of commercial polymer-based sensors. This work demonstrates the readiness of the developed RH sensor technology for industrialization.

摘要

具有简单转换原理的湿度传感器的发展引起了科学研究人员和工业公司的极大兴趣。制备了基于具有不同厚度和表面形貌的聚酰亚胺传感材料的电容式湿度传感器。通过使用氧气等离子体蚀刻工艺,将传感层的表面形貌从平坦变为粗糙,然后变为称为纳米草的纳米结构。通过电容变化,相对湿度(RH)传感器选择性地响应水蒸气的存在。通过傅立叶变换红外光谱研究聚酰亚胺与水分子之间的相互作用。使用气体混合装置和评估套件实现了对制备的电容式湿度传感器性能的完整表征。在 5 至 85%的范围内,发现测量电容与 RH 水平之间存在线性相关性。湿度传感层的形态被揭示为影响传感器性能的重要参数。事实证明,由于其快速的响应和恢复时间,纳米草状结构对于检测 RH 最为有效,其响应和恢复时间可与甚至优于商业聚合物基传感器的响应和恢复时间相媲美。这项工作证明了所开发的 RH 传感器技术已准备好实现工业化。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df0e/5982669/8e7dcfbd19d1/sensors-18-01516-g001.jpg

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