一种基于醚的新型锂硫电池电解质，使用 S@pPAN 阴极。
A new ether-based electrolyte for lithium sulfur batteries using a S@pPAN cathode.
机构信息
Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China.
出版信息
Chem Commun (Camb). 2018 May 24;54(43):5478-5481. doi: 10.1039/c8cc02552e.
A new electrolyte composed of 4 M LiFSI in dibutyl ether (DBE) is proposed for Li-S batteries. Dissolution of lithium polysulfides is definitely inhibited by DBE. More impressively, the electrolyte ensures a high Coulombic efficiency for Li deposition/stripping (∼99.2%) without dendrite growth. Enhanced cycling stability is demonstrated when coupled with a sulfurized poly(acrylonitrile) (S@pPAN) cathode. This electrolyte offers new insight into electrolyte design for high performance Li-S batteries.
一种由 4 M LiFSI 和二丁醚（DBE）组成的新型电解液被提议用于 Li-S 电池。DBE 肯定会抑制多硫化物的溶解。更令人印象深刻的是，该电解液确保了 Li 沉积/剥离的高库仑效率（约 99.2%），而没有枝晶生长。当与硫代聚丙烯腈（S@pPAN）阴极结合使用时，展示了增强的循环稳定性。这种电解液为高性能 Li-S 电池的电解液设计提供了新的思路。
Zotero 插件