RWTH Aachen University, Chemical Process Engineering, Forckenbeckstrasse 51, 52074 Aachen, Germany.
RWTH Aachen University, Chemical Process Engineering, Forckenbeckstrasse 51, 52074 Aachen, Germany; DWI - Leibniz Institute for Interactive Materials, Forckenbeckstr. 50, 52074 Aachen, Germany.
Water Res. 2018 Oct 1;142:18-25. doi: 10.1016/j.watres.2018.05.007. Epub 2018 May 11.
Decentralized drinking water treatment is limited by supply of service, consumables, spare parts and in particular, power. Therefore, gravity-driven dead-end ultrafiltration is applied to purify surface water with high suspended solid loading. To obtain high flux in the long term, an effective membrane backwash is mandatory. Also, disinfection and cleaning is required regularly. Here we propose a new process coping with these particular challenges in decentralized water production: Temperature Enhanced Backwash. Herein, the membrane is backwashed at elevated temperature and corresponding steam pressure. A mathematical description of the Temperature Enhanced Backwash reveals that membrane pores are filled predominantly with liquid phase, irrespectively of whether membranes are charged with saturated steam or boiling liquid. A steam - water mixture is discharged at the module outlet suggesting evaporation at the end of the pores. This evaporation at membrane - fluid interface supposedly creates high volume fluxes shearing off potential fouling layers. Combined with gravity-driven filtration, the overall process potentially can cope with highly intermittent electrical power supply or even its absence. The methodology shows competitive cleaning efficacy compared to mechanical backwashing as demonstrated experimentally using silica nanoparticles, humic acid and river water.
分散式饮用水处理受到服务供应、消耗品、备件以及特别是电力的限制。因此,采用重力驱动的死端超滤来净化悬浮物负荷较高的地表水。为了长期获得高流量,必须进行有效的膜反洗。此外,还需要定期进行消毒和清洗。在这里,我们提出了一种新的工艺,可以应对分散式水生产中的这些特殊挑战:温度增强反洗。在此过程中,膜在升高的温度和相应的蒸汽压力下进行反洗。对温度增强反洗的数学描述表明,无论膜是否充满饱和蒸汽或沸腾液体,膜孔主要填充的是液相。蒸汽-水混合物从模块出口排出,表明在孔的末端发生了蒸发。这种在膜-流体界面的蒸发会产生高体积通量,剪切掉潜在的污垢层。与重力驱动过滤相结合,该整体工艺可以潜在应对高度间歇性的电力供应,甚至可以应对其缺失。该方法显示出与机械反洗相当的清洁效果,这通过使用硅纳米颗粒、腐殖酸和河水进行的实验得到了证明。