Department of Mechanical Engineering, Stanford University, Stanford, California 94305, USA.
Nanoscale. 2018 Jun 14;10(23):11117-11122. doi: 10.1039/c8nr01788c.
Thermal conduction in complex periodic nanostructures remains a key area of open questions and research, and a particularly provocative and challenging detail is the impact of nanoscale material volumes that do not lie along the optimal line of sight for conduction. Here, we experimentally study thermal transport in silicon nanoladders, which feature two orthogonal heat conduction paths: unobstructed line-of-sight channels in the axial direction and interconnecting bridges between them. The nanoladders feature an array of rectangular holes in a 10 μm long straight beam with a 970 nm wide and 75 nm thick cross-section. We vary the pitch of these holes from 200 nm to 1100 nm to modulate the contribution of bridges to the net transport of heat in the axial direction. The effective thermal conductivity, corresponding to reduced heat flux, decreases from ∼45 W m-1 K-1 to ∼31 W m-1 K-1 with decreasing pitch. By solving the Boltzmann transport equation using phonon mean free paths taken from ab initio calculations, we model thermal transport in the nanoladders, and experimental results show excellent agreement with the predictions to within ∼11%. A combination of experiments and calculations shows that with decreasing pitch, thermal transport in nanoladders approaches the counterpart in a straight beam equivalent to the line-of-sight channels, indicating that the bridges constitute a thermally dead volume. This study suggests that ballistic effects are dictated by the line-of-sight channels, providing key insights into thermal conduction in nanostructured metamaterials.
复杂周期纳米结构中的热传导仍然是一个悬而未决的问题和研究的关键领域,一个特别有争议和具有挑战性的细节是纳米级材料体积的影响,这些体积不在导热的最佳视线范围内。在这里,我们通过实验研究了硅纳米梯的热传输,它具有两个正交的热传导路径:轴向的无阻碍视线通道和它们之间的连接桥。纳米梯在一个 10 μm 长的直梁上有一个矩形孔阵列,其横截面为 970nm 宽和 75nm 厚。我们从 200nm 到 1100nm 改变这些孔的间距,以调节桥对轴向净热传输的贡献。有效热导率,对应于减小的热通量,随着间距的减小从约 45 W m-1 K-1 减小到约 31 W m-1 K-1。通过使用从第一性原理计算中获得的声子平均自由程来求解玻尔兹曼输运方程,我们对纳米梯中的热传输进行了建模,实验结果与预测值的吻合度在 11%以内。实验和计算的结合表明,随着间距的减小,纳米梯中的热传输接近与视线通道相当的直梁的对应物,表明桥构成了热死体积。这项研究表明,弹道效应由视线通道决定,为理解纳米结构超材料中的热传导提供了关键的见解。