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[北京室内/室外空气中细颗粒物(PM₂.₅)中有机碳和元素碳的特征]

[Characteristics of organic and elemental carbon in the indoor/outdoor air PM_(2. 5) in Beijing].

作者信息

Tao Jing, Wang Yu, Wei Jianrong, Zhang Riu, Li Ting

机构信息

Beijing Center for Diseases Control and Prevention, Beijing 100013, China.

出版信息

Wei Sheng Yan Jiu. 2016 Sep;45(5):795-806.

Abstract

OBJECTIVE

To study the characteristics of indoor/outdoor organic and elemental carbon in the PM_(2. 5).

METHODS

Seven type regions were selected in Beijing. The samples of OC and EC in PM_(2. 5)were collected and were measured in the indoor /outdoor of seven type areas respectively from May 2013 to April 2014.

RESULTS

The overall concentrations( median and P25-P75) of indoor OC and EC in PM_(2. 5)were 13. 4 μg /m3( 8. 82- 26. 6 μg/m3) and 3. 79 μg /m3( 2. 09-6. 98 μg /m3), and the concentrations of outdoor OC and EC were 15. 4 μg / m3( 10. 6- 35. 2 μg /m3) and 4. 96 μg/m3( 2. 92-9. 39 μg/m3), respectively. Indoor and outdoor OC were the dominant species occupying78% and 73% of TC, respectively. Outdoor carbonaceous matter was higher than indoor matter and the concentration of OC was higher than that of EC. The outdoor OC concentration during heating period was the highest in all seasons and the concentrations ofother seasons found no difference. The outdoor OC concentration in weekend was high, while was lower during the period of Monday to Wednesday. The outdoor OC concentrations of seven type areas were different and the pollutants from dust area, aviation fuel emissions, industry and light industry were highest, followed by ones from vehicle emissions, coal-burning power plant, and one in clean district was the lowest. There were high linear relationships between outdoor OC and outdoor EC( r = 0. 886), between indoor OC and outdoor OC( r = 0. 915), between indoor EC and outdoor EC( r =0. 894), between carbonaceous matter and PM_(2. 5)( rOC-PM_(2. 5)= 0. 785, rEC-PM 2. 5= 0. 775), respectively. The indoor OC to outdoor OC ratio in summer was the highest in all seasons and the ratios of other seasons found no difference. The outdoor OC to outdoor EC ratio in heating period was highest, and was lowest in summer.

CONCLUSION

We should pay attention to OC and EC pollution in Beijing air, should strengthen the protection to OC pollutants during the haze, and should take some measures to control the pollution of OC.

摘要

目的

研究细颗粒物(PM₂.₅)中室内/室外有机碳和元素碳的特征。

方法

在北京选取7类区域。于2013年5月至2014年4月分别在7类区域的室内/室外采集PM₂.₅中有机碳(OC)和元素碳(EC)的样本并进行测定。

结果

PM₂.₅中室内OC和EC的总体浓度(中位数及P25 - P75)分别为13.4 μg/m³(8.82 - 26.6 μg/m³)和3.79 μg/m³(2.09 - 6.98 μg/m³),室外OC和EC的浓度分别为15.4 μg/m³(10.6 - 35.2 μg/m³)和4.96 μg/m³(2.92 - 9.39 μg/m³)。室内和室外OC均为主要成分,分别占总碳(TC)的78%和73%。室外碳质物质高于室内,且OC浓度高于EC。采暖期室外OC浓度在所有季节中最高,其他季节浓度无差异。周末室外OC浓度较高,周一至周三期间较低。7类区域的室外OC浓度不同,来自沙尘区域、航空燃油排放、工业和轻工业的污染物最高,其次是来自机动车排放、燃煤电厂的,清洁区域的最低。室外OC与室外EC之间(r = 0.886)、室内OC与室外OC之间(r = 0.915)、室内EC与室外EC之间(r = 0.894)、碳质物质与PM₂.₅之间(rOC - PM₂.₅ = 0.785,rEC - PM₂.₅ = 0.775)均存在高度线性关系。夏季室内OC与室外OC的比值在所有季节中最高,其他季节的比值无差异。采暖期室外OC与室外EC的比值最高,夏季最低。

结论

应关注北京空气中OC和EC污染,在雾霾期间应加强对OC污染物的防护,并采取措施控制OC污染。

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