通过远程杂芳基邻位迁移实现烯烃的催化、无金属杂芳基烷基化。
Catalytic, metal-free alkylheteroarylation of alkenes via distal heteroaryl ipso-migration.
机构信息
Key Laboratory of Chemistry in Ethnic Medicinal Resources, State Ethnic Affairs Commission & Ministry of Education, Yunnan Minzu University, Kunming, Yunnan Province 650500, P. R. China.
College of Life Science, Northwest University, Xi'an, Shanxi Province 710069, P. R. China.
出版信息
Chem Commun (Camb). 2018 Jul 11;54(54):7499-7502. doi: 10.1039/c8cc03911a. Epub 2018 Jun 20.
A new direct alkylheteroarylation of alkenes with simple alkylnitriles via distal heteroaryl ipso-migration has been accomplished under metal-free conditions, in which inexpensive alkylnitriles served as radical precursors, which together with ease of operation makes this process a very practical protocol.
在无金属条件下，通过远程杂芳基 ipso-迁移，实现了烯烃与简单烷基腈的新的直接烷基杂芳基化反应，其中廉价的烷基腈作为自由基前体，这与操作简便性一起使该过程成为非常实用的方案。
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